Two-photon absorption characterization and comparison of Au(I) fluorenyl benzothiazole complexes in the visible wavelength regime

被引：2
作者：
Ensley, Trenton R. [1 ]
O'Donnell, Ryan M. [1 ]
Mihaly, Joseph J. [2 ,3 ]
Haley, Joy E. [4 ]
Grusenmeyer, Tod A. [4 ]
Gray, Thomas G. [2 ]
机构：
[1] DEVCOM US Army Res Lab, Sensors & Electron Devices Directorate, Adelphi, MD 20783 USA
[2] Case Western Reserve Univ, Dept Chem, Cleveland, OH 44106 USA
[3] PPG Ind Inc, Cleveland, OH 44111 USA
[4] US Air Force Res Lab, Mat & Mfg Directorate, Dayton, OH 45433 USA
来源：
APPLIED OPTICS | 2021年 / 60卷 / 25期
关键词：
REVERSE SATURABLE ABSORPTION; EXCITED-STATE ABSORPTION; 3RD-ORDER OPTICAL NONLINEARITIES; ORGANOMETALLIC COMPLEXES; CUBIC HYPERPOLARIZABILITIES; PLATINUM(II) ACETYLIDES; ANCILLARY LIGAND; CROSS-SECTIONS; DATA STORAGE; PHOTOPHYSICS;
D O I：
10.1364/AO.427968
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
We use the two-photon excited fluorescence method to determine the two-photon absorption (2PA) cross sections of three series of (fluorenyl benzothiazole) gold(I) complexes in the visible wavelength range from 570 to 700 nm. We compare the effect of ancillary ligand substitutions on the 2PA magnitudes and find that the ancillary ligand does not drastically affect either the magnitude or the shape of 2PA. Even so, moderate 2PA cross sections were measured that ranged from 10 to 1000 s of GM (Goppert-Mayer, = 10(-50) cm(4)s/photon), making these types of complexes nonlinear optical materials for two-photon absorbing applications. (C) 2021 Optical Society of America under the terms of the OSA Open Access Publishing Agreement
引用
收藏
页码：G199 / G206
页数：8
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