Synthesis and rutilelike structure of [Cd(tcm)(hmt)(H2O)](tcm) (tcm- = tricyanomethanide, C(CN)3-; hmt = hexamethylenetetramine)

被引：63
作者：
Batten, SR [1 ]
Hoskins, BF [1 ]
Robson, R [1 ]
机构：
[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia
来源：
INORGANIC CHEMISTRY | 1998年 / 37卷 / 13期
关键词：
D O I：
10.1021/ic980059v
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The three-dimensional coordination polymer [Cd(tcm)(hmt)(H(2)O)](tcm) (tcm(-) = tricyanomethanide, C(CN)(3)(-); hmt = hexamethylenetetramine) has a rutilelike topology, with octahedral centers (cadmium atoms) and trigonal centers (hmt ligands and half the tcm anions) in the ratio 1:2. One of the connections of the three-connecting hmt ligands is a hydrogen-bonding interaction with coordinated water ligands.
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页码：3432 / +
页数：4
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