Transformations of the picrotoxanes: The synthesis of corianin and structural analogues from picrotoxinin

被引：18

作者：

Krische, MJ ^{[1
]}

Trost, BM ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 25期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

corianin; picrotoxinin; picrotoxane; enyne cycloisomerization; palladium catalysis; transition metal catalysis;

D O I：

10.1016/S0040-4020(98)00350-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The neurochemically active picrotoxane sesquiterpene corianin and several structural analogues have been prepared from inexpensive, commercially available picrotoxin. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7109 / 7120

页数：12

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