Product channels of the HCCO+NO reaction

被引：19

作者：

Meyer, JP ^{[1
]}

Hershberger, JF ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem & Mol Biol, Fargo, ND 58105 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2005年 / 109卷 / 17期

关键词：

D O I：

10.1021/jp040503h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The product branching ratio of the HCCO + NO reaction was investigated using the laser photolysis/infrared absorption technique. Ethyl ethynyl ether (C2H5OCCH) was used as the HCCO radical precursor. Transient infrared detection Of CO, CO2, and HCNO products was used to determine the following branching ratios at 296 K: φ(CO+HCNO) = 0.78 ± 0.04 and φ(CO2+HCN) = 0.22 ± 0.04. These values are in good agreement with some recent ab initio calculations.

引用

页码：8363 / 8366

页数：4

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