Ultralight and flexible supercapacitor electrodes made from Ni(OH)2 nanosheets doped with Ag nanoparticle/3D graphene composite

被引:23
作者
Lan, Wei [1 ,2 ]
Sun, Yaru [1 ]
Chen, Youxin [1 ]
Wang, Junya [1 ]
Tang, Guomei [1 ]
Dou, Wei [3 ]
Su, Qing [1 ]
Xie, Erqing [1 ]
机构
[1] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
[2] Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
[3] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
关键词
NICKEL FOAM; PERFORMANCE; DEPOSITION; DESIGN; OXIDE; FILM;
D O I
10.1039/c5ra00317b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A composite of Ni(OH)(2) nanosheets doped with Ag nanoparticle/3D graphene (Ag/Ni(OH)(2)/3DG) was synthesized by a combination of chemical vapor deposition and a hydrothermal process. The Ag/Ni(OH)(2)/3DG composite is light, flexible and has a high conductivity. It can be utilized directly for supercapacitor electrodes (including current collectors) without using binder materials or conductive agents. Doping the Ni(OH)(2) nanosheets with Ag nanoparticles can improve the conductivity, which enhances the specific capacitance of the hybrid electrode accordingly. Electrochemical tests show a high specific capacitance of 2167 F g(-1) scaled to the total mass of the electrodes at 10 A g(-1) current density, a good rate capability and an excellent cycling performance of 98% capacitance retention over 1000 cycles at 25 A g(-1) current.
引用
收藏
页码:20878 / 20883
页数:6
相关论文
共 27 条
[1]   Layered inorganic organic-hybrid material based on reduced graphene oxide and α-Ni(OH)2 for high performance supercapacitor electrodes [J].
Bag, Sourav ;
Raj, C. Retna .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (42) :17848-17856
[2]   Synthesis of Large-Area Graphene Layers on Poly-Nickel Substrate by Chemical Vapor Deposition: Wrinkle Formation [J].
Chae, Seung Jin ;
Guenes, Fethullah ;
Kim, Ki Kang ;
Kim, Eun Sung ;
Han, Gang Hee ;
Kim, Soo Min ;
Shin, Hyeon-Jin ;
Yoon, Seon-Mi ;
Choi, Jae-Young ;
Park, Min Ho ;
Yang, Cheol Woong ;
Pribat, Didier ;
Lee, Young Hee .
ADVANCED MATERIALS, 2009, 21 (22) :2328-+
[3]   The role and utilization of pseudocapacitance for energy storage by supercapacitors [J].
Conway, BE ;
Birss, V ;
Wojtowicz, J .
JOURNAL OF POWER SOURCES, 1997, 66 (1-2) :1-14
[4]   Porous CoO nanobundles composited with 3D graphene foams for supercapacitors electrodes [J].
Deng, Wei ;
Sun, Yaru ;
Su, Qing ;
Xie, Erqing ;
Lan, Wei .
MATERIALS LETTERS, 2014, 137 :124-127
[5]   Porous CoO nanostructures grown on three-dimension graphene foams for supercapacitors electrodes [J].
Deng, Wei ;
Lan, Wei ;
Sun, Yaru ;
Su, Qing ;
Xie, Erqing .
APPLIED SURFACE SCIENCE, 2014, 305 :433-438
[6]   Graphene nanosheets as electrode material for electric double-layer capacitors [J].
Du, Xian ;
Guo, Peng ;
Song, Huaihe ;
Chen, Xiaohong .
ELECTROCHIMICA ACTA, 2010, 55 (16) :4812-4819
[7]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[8]  
Ghaemi M, 2010, INT J ELECTROCHEM SC, V5, P131
[9]   Graphene decorated with Ni(OH)2 and Ag deposited Ni(OH)2 stacked nanoplate for supercapacitor application [J].
Ghosh, Debasis ;
Giri, Soumen ;
Mandal, Avinandan ;
Das, Chapal Kumar .
CHEMICAL PHYSICS LETTERS, 2013, 573 :41-47
[10]   Design and tailoring of the nanotubular arrayed architecture of hydrous RuO2 for next generation supercapacitors [J].
Hu, Chi-Chang ;
Chang, Kuo-Hsin ;
Lin, Ming-Champ ;
Wu, Yung-Tai .
NANO LETTERS, 2006, 6 (12) :2690-2695