Extended Polyoxometalate Framework Solids: Two Mn(II)-Linked {P8W48} Network Arrays

被引：76

作者：

Mitchell, Scott G. ^{[1
]}

Boyd, Thomas ^{[1
]}

Miras, Haralampos N. ^{[1
]}

Long, De-Liang ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

HETEROPOLYANION; NUCLEATION; MANGANESE; COBALT;

D O I：

10.1021/ic101472s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two polyoxometalate open framework (POMOF) materials have been synthesized using a secondary building unit (SBU) approach that facilitates the convergent assembly of multidimensional framework materials using a preassembled anionic SBU {P8W48}, with integrated "pore" 1 nm in diameter, and electrophilic manganese {Mn2+} linkers. This yields two new POMOFS with augmented hexagonal tiling (2 and 3), related to a known three-dimensional (3D) cubic array K18Li6[Mn-8(II)(H2O)(48)P8W48O184].108H(2)O (1), K-12[Mn-14(II)(H2O)(30)P8W48O184].111H(2)O (2), and K8Li4[Mn-1.4(II)(H2O)(26)P(8)W(48)O(18)4].105H(2)O (3). These frameworks have been crystallized from aqueous Li-buffered solutions of {P8W48} and Mn-II(ClO4)(2).6H(2)O via careful control of the synthetic strategy akin to a crystal engineering approach using cation and temperature control to isolate different material architectures shown by compounds 1-3.

引用

页码：136 / 143

页数：8

共 36 条

[11] Structure-related frustrated magnetism of nanosized polyoxometalates: aesthetics and properties in harmony [J].

Koegerler, Paul ;

Tsukerblat, Boris ;

Mueller, Achim .

DALTON TRANSACTIONS, 2010, 39 (01) :21-36

[12]

Liw J., 1992, J CHEM SOC DA, P1901

[13] Towards polyoxometalate-integrated nanosystems [J].

Long, De-Liang ;

Cronin, Leroy .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (14) :3699-3706

[14] Polyoxometalates: Building Blocks for Functional Nanoscale Systems [J].

Long, De-Liang ;

Tsunashima, Ryo ;

Cronin, Leroy .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (10) :1736-1758

[15] The pervasive chemistry of metal-organic frameworks [J].

Long, Jeffrey R. ;

Yaghi, Omar M. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1213-1214

[16] Organoruthenium derivative of the cyclic [H7P8W48O184]33- anion:: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27- [J].

Mal, Sib Sankar ;

Nsouli, Nadeen H. ;

Dickman, Michael H. ;

Kortz, Ulrich .

DALTON TRANSACTIONS, 2007, (25) :2627-2630

[17] The wheel-shaped Cu20 tungstophosphate [Cu20Cl(OH)24(H2O)12(P8W48O184)]25- ion [J].

Mal, SS ;

Kortz, U .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (24) :3777-3780

[18] Zeolitic Polyoxometalate-Based Metal-Organic Frameworks (Z-POMOFs): Computational Evaluation of Hypothetical Polymorphs and the Successful Targeted Synthesis of the Redox-Active Z-POMOF1 [J].

Marleny Rodriguez-Albelo, L. ;

Rabdel Ruiz-Salvador, A. ;

Sampieri, Alvaro ;

Lewis, Dewi W. ;

Gomez, Ariel ;

Nohra, Brigitte ;

Mialane, Pierre ;

Marrot, Jerome ;

Secheresse, Francis ;

Mellot-Draznieks, Caroline. ;

Biboum, Rosa Ngo ;

Keita, Bineta ;

Nadjo, Louis ;

Dolbecq, Anne .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :16078-16087

[19] Manganous heteropolytungstates. Synthesis and heteroatom effects in Wells-Dawson-derived sandwich complexes [J].

Mbomekalle, IM ;

Keita, B ;

Nadjo, L ;

Berthet, P ;

Neiwert, WA ;

Hill, CL ;

Ritorto, MD ;

Anderson, TM .

DALTON TRANSACTIONS, 2003, (13) :2646-2650

[20]

Mitchell SG, 2010, NAT CHEM, V2, P308, DOI [10.1038/nchem.581, 10.1038/NCHEM.581]

← 1 2 3 4 →