Extended Polyoxometalate Framework Solids: Two Mn(II)-Linked {P8W48} Network Arrays

被引：76

作者：

Mitchell, Scott G. ^{[1
]}

Boyd, Thomas ^{[1
]}

Miras, Haralampos N. ^{[1
]}

Long, De-Liang ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

HETEROPOLYANION; NUCLEATION; MANGANESE; COBALT;

D O I：

10.1021/ic101472s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two polyoxometalate open framework (POMOF) materials have been synthesized using a secondary building unit (SBU) approach that facilitates the convergent assembly of multidimensional framework materials using a preassembled anionic SBU {P8W48}, with integrated "pore" 1 nm in diameter, and electrophilic manganese {Mn2+} linkers. This yields two new POMOFS with augmented hexagonal tiling (2 and 3), related to a known three-dimensional (3D) cubic array K18Li6[Mn-8(II)(H2O)(48)P8W48O184].108H(2)O (1), K-12[Mn-14(II)(H2O)(30)P8W48O184].111H(2)O (2), and K8Li4[Mn-1.4(II)(H2O)(26)P(8)W(48)O(18)4].105H(2)O (3). These frameworks have been crystallized from aqueous Li-buffered solutions of {P8W48} and Mn-II(ClO4)(2).6H(2)O via careful control of the synthetic strategy akin to a crystal engineering approach using cation and temperature control to isolate different material architectures shown by compounds 1-3.

引用

页码：136 / 143

页数：8

共 36 条

[1] Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9- and [Ln(β2-SiW11O39)2]13- (LnIII = Tb, Dy, Ho, Er, Tm, and Yb) [J].

AlDamen, Murad A. ;

Cardona-Serra, Salvador ;

Clemente-Juan, Juan M. ;

Coronado, Eugenio ;

Gaita-Arino, Alejandro ;

Marti-Gastaldo, Carlos ;

Luis, Fernando ;

Montero, Oscar .

INORGANIC CHEMISTRY, 2009, 48 (08) :3467-3479

[2] Cobalt, Manganese, Nickel, and Vanadium Derivatives of the Cyclic 48-Tungsto-8-Phosphate [H7P8W48O184]33- [J].

Bassil, Bassem S. ;

Ibrahim, Masooma ;

Mal, Sib Sankar ;

Suchopar, Andreas ;

Biboum, Rosa Ngo ;

Keita, Bineta ;

Nadjo, Louis ;

Nellutla, Saritha ;

van Tol, Johan ;

Dalal, Naresh S. ;

Kortz, Ulrich .

INORGANIC CHEMISTRY, 2010, 49 (11) :4949-4959

[3] Crystal structure and replacement reaction of coordinated water molecules of the heteropoly compounds of sandwich-type tungstoarsenates [J].

Bi, LH ;

Wang, EB ;

Peng, J ;

Huang, RD ;

Xu, L ;

Hu, CW .

INORGANIC CHEMISTRY, 2000, 39 (04) :671-679

[4] Highly efficient catalysts in directed oxygen-transfer processes:: Synthesis, structures of novel manganese-containing heteropolyanions, and applications in regioselective epoxidation of dienes with hydrogen peroxide [J].

Bösing, M ;

Nöh, A ;

Loose, I ;

Krebs, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (29) :7252-7259

[5] THE ANALYTICAL CALCULATION OF ABSORPTION IN MULTIFACETED CRYSTALS [J].

CLARK, RC ;

REID, JS .

ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :887-897

[6] A NEW CROWN HETEROPOLYANION, K28LI5H7P8W48O184.92H2O - SYNTHESIS, STRUCTURE, AND PROPERTIES [J].

CONTANT, R ;

TEZE, A .

INORGANIC CHEMISTRY, 1985, 24 (26) :4610-4614

[7]

Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]

[8] Structural, Physicochemical, and Reactivity Properties of an All-inorganic, Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation [J].

Geletii, Yurii V. ;

Besson, Claire ;

Hou, Yu ;

Yin, Qiushi ;

Musaev, Djamaladdin G. ;

Quinonero, David ;

Cao, Rui ;

Hardcastle, Kenneth I. ;

Proust, Anna ;

Koegerler, Paul ;

Hill, Craig L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (47) :17360-17370

[9] Polyoxotungstate- encapsulated Gd6 and Yb10 complexes [J].

Hussain, Firasat ;

Gable, Robert W. ;

Speldrich, Manfred ;

Koegerler, Paul ;

Boskovic, Colette .

CHEMICAL COMMUNICATIONS, 2009, (03) :328-330

[10] Electron transfer behavioir of multi-iron sandwich-type polyoxometalates and electrocatalytic reduction reactions [J].

Keita, B ;

Mbomekalle, IM ;

Lu, YW ;

Nadjo, L ;

Berthet, P ;

Anderson, TM ;

Hill, CL .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (17) :3462-3475

← 1 2 3 4 →