Reactivity of a stable copper-dioxygen complex

被引：35

作者：

Iovan, Diana A. ^{[1
]}

Wrobel, Alexandra T. ^{[1
]}

McClelland, Arthur A. ^{[2
]}

Scharf, Austin B. ^{[1
]}

Edouard, Guy A. ^{[1
]}

Betley, Theodore A. ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, 12 Oxford St, Cambridge, MA 02138 USA

[2] Harvard Univ, Ctr Nanoscale Syst, 11 Oxford St, Cambridge, MA 02138 USA

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 74期

关键词：

METAL-COMPLEXES; BIS(MU-OXO) COMPLEXES; MECHANISTIC INSIGHTS; SUPEROXO COMPLEX; C-H; LIGAND; ADDUCT; SPECTROSCOPY; OXYGENATION; ACTIVATION;

D O I：

10.1039/c7cc05014c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the isolation of a roomtemperature stable dipyrromethene Cu(O-2) complex featuring a side-on O-2 coordination. Reactivity studies highlight the unique ability of the dioxygen adduct for both hydrogen-atom abstraction and acid/base chemistry towards phenols, demonstrating that side-on superoxide species can be reactive entities.

引用

页码：10306 / 10309

页数：4

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