Visible-Light-Driven Aerobic Oxidation of Amines to Nitriles over Hydrous Ruthenium Oxide Supported on TiO2

被引：65
作者：
Ovoshchnikov, Daniil S. [1 ]
Donoeva, Baira G. [1 ,2 ]
Golovko, Vladimir B. [1 ,2 ]
机构：
[1] Univ Canterbury, Dept Chem, Christchurch 8140, New Zealand
[2] MacDiarmid Inst Adv Mat & Nanotechnol, Wellington 6140, New Zealand
来源：
ACS CATALYSIS | 2015年 / 5卷 / 01期
关键词：
photocatalysis; amine oxidation; ruthenium; nitrile; aerobic oxidation; SURFACE-PLASMON RESONANCE; MOLECULAR-OXYGEN; PHOTOCATALYTIC DEGRADATION; HETEROGENEOUS CATALYST; ALLOY NANOPARTICLES; GOLD NANOPARTICLES; ORGANIC-COMPOUNDS; ELECTRON-TRANSFER; TITANIUM-DIOXIDE; REDUCTION;
D O I：
10.1021/cs501186n
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Aerobic oxidation of amines to nitriles under visible light irradiation was catalyzed by supported hydrous ruthenium oxide catalyst. Both LED (blue, green, or red) and the Sun were effective light sources for the transformation of benzylic and aliphatic arnines to the corresponding nitriles under atmospheric pressure of O. Water can be used as a solvent instead of toluene without the loss of activity and selectivity.
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页码：34 / 38
页数：5
相关论文
共 62 条
[1]   Dual optical functionality of local surface plasmon resonance for RuO2 nanoparticle-ZnO nanorod hybrids grown by atomic layer deposition [J].
Bang, Seokhwan ;
Lee, Seungjun ;
Park, Taeyoung ;
Ko, Youngbin ;
Shin, Seokyoon ;
Yim, Sang-Youp ;
Seo, Hyungtak ;
Jeon, Hyeongtag .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (28) :14141-14148
[2]   Noble Metal Nanocrystals: Plasmon Electron Transfer Photochemistry and Single-Molecule Raman Spectroscopy [J].
Brus, Louis .
ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (12) :1742-1749
[3]   What is a green solvent?: A comprehensive framework for the environmental assessment of solvents [J].
Capello, Christian ;
Fischer, Ulrich ;
Hungerbuehler, Konrad .
GREEN CHEMISTRY, 2007, 9 (09) :927-934
[4]   Semiconductor-mediated photodegradation of pollutants under visible-light irradiation [J].
Chen, Chuncheng ;
Ma, Wanhong ;
Zhao, Jincai .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (11) :4206-4219
[5]   An alternative pathway for production of acetonitrile: ruthenium catalysed aerobic dehydrogenation of ethylamine [J].
Corker, Emily C. ;
Mentzel, Uffe V. ;
Mielby, Jerrik ;
Riisager, Anders ;
Fehrmann, Rasmus .
GREEN CHEMISTRY, 2013, 15 (04) :928-933
[6]   Electronic and optical properties of RuO2 and IrO2 [J].
de Almeida, JS ;
Ahuja, R .
PHYSICAL REVIEW B, 2006, 73 (16)
[7]  
Fatiadi A.J., 1983, PREPARATION SYNTHETI, V2, P1057
[8]   Nitrile-Containing Pharmaceuticals: Efficacious Roles of the Nitrile Pharmacophore [J].
Fleming, Fraser F. ;
Yao, Lihua ;
Ravikumar, P. C. ;
Funk, Lee ;
Shook, Brian C. .
JOURNAL OF MEDICINAL CHEMISTRY, 2010, 53 (22) :7902-7917
[9]   MAGNETIC AND OTHER STUDIES OF RUTHENIUM DIOXIDE AND ITS HYDRATE [J].
FLETCHER, JM ;
GARDNER, WE ;
GREENFIELD, BF ;
HOLDOWAY, MJ ;
RAND, MH .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (03) :653-+
[10]  
Foote C.S., 1979, SINGLET OXYGEN, P139
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