Inverse gas chromatography studies of alkali cation exchanged X-zeolites

被引：28
|
作者：
Xie, JH [1 ]
Bousmina, M [1 ]
Xu, GY [1 ]
Kaliaguine, S [1 ]
机构：
[1] Univ Laval, Dept Chem Engn, St Foy, PQ G1K 7P4, Canada
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 135卷 / 02期
基金：
加拿大自然科学与工程研究理事会;
关键词：
zeolites; basicity; acidity; inverse gas chromatography; specific interaction; benzene; toluene; chloroform;
D O I：
10.1016/S1381-1169(97)00303-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The base strength of alkali cation exchanged X-zeolites was investigated using the IGC technique. The results show that IGC can give information about the acid-base interaction with polar probe molecules. The specific interaction (I-sp, mJ/m(2)) between zeolites and benzene, toluene, chloroform can be correlated to the strength of acid-base interaction. (C) 1988 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：187 / 197
页数：11
相关论文
共 50 条
  • [1] MICROCALORIMETRIC CHARACTERIZATION OF THE BASICITY IN ALKALI-EXCHANGED X-ZEOLITES
    HUANG, MM
    KALIAGUINE, S
    MUSCAS, M
    AUROUX, A
    JOURNAL OF CATALYSIS, 1995, 157 (01) : 266 - 269
  • [2] Cryoadsorption of hydrogen on divalent cation-exchanged X-zeolites
    Li, Jing
    Wu, Erdong
    Song, Jiangwei
    Xiao, Fengshou
    Geng, Changjian
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (13) : 5458 - 5465
  • [3] PHYSICOCHEMICAL PROPERTIES OF ALKALI-METAL EXCHANGED TYPE X-ZEOLITES
    TAMHANKAR, SS
    SHIRALKAR, VP
    JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1994, 17 (03): : 221 - 235
  • [4] BASE AND ACID SITES IN ALKALINE-EARTH CATION-EXCHANGED X-ZEOLITES
    XIE, J
    KALIAGUINE, S
    CATALYSIS LETTERS, 1994, 29 (3-4) : 281 - 291
  • [5] FORMATION OF METAL-CLUSTERS IN ALKALINE-EARTH-CATION-EXCHANGED X-ZEOLITES
    XU, B
    KEVAN, L
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (09): : 3647 - 3652
  • [6] ISOMERIZATION OF BUTENES OVER ION-EXCHANGED X-ZEOLITES
    CROSS, NE
    KEMBALL, C
    LEACH, HF
    ADVANCES IN CHEMISTRY SERIES, 1971, (102): : 389 - &
  • [7] CARBOHYDRATE SEPARATION BY X-ZEOLITES - CATION AND SOLVENT EFFECTS
    WORTEL, TM
    VANBEKKUM, H
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1978, 97 (06): : 156 - 158
  • [8] FAR-INFRARED STUDY OF METAL-PARTICLE FORMATION IN ALKALI-METAL CATION-EXCHANGED X-ZEOLITES EXPOSED TO SODIUM VAPOR
    XU, B
    KEVAN, L
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1992, 88 (12): : 1695 - 1699
  • [9] FOURIER-TRANSFORM INFRARED STUDY ON THE ENCAPSULATION OF CARBON-MONOXIDE IN CATION-EXCHANGED X-ZEOLITES
    KAMBLE, VS
    GUPTA, NM
    KARTHA, VB
    IYER, RM
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (07): : 1143 - 1150
  • [10] Characterization of Co, Fe and Mn-exchanged zeolites by inverse gas chromatography
    Díaz, E
    Ordóñez, S
    Vega, A
    Coca, J
    JOURNAL OF CHROMATOGRAPHY A, 2004, 1049 (1-2) : 161 - 169
12345