Synthesis, characterization, and electrochemical properties of the modified graphene oxide with 4,4′-methylenedianiline

被引：26

作者：

Nikkhah, Shiva ^{[1
]}

Tahermansouri, Hasan ^{[1
]}

Chekin, Fereshteh ^{[1
]}

机构：

[1] Islamic Azad Univ, Ayatollah Amoli Branch, Dept Chem, Amol, Iran

来源：

MATERIALS LETTERS | 2018年 / 211卷

关键词：

Carbon materials; Graphene oxide; Functional; Electrocatalysis; OXYGEN EVOLUTION REACTION; HIGH-PERFORMANCE; NANOWIRE ARRAY; NANOCOMPOSITES; BATTERIES; PH;

D O I：

10.1016/j.matlet.2017.10.037

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Graphene oxide (GO) was modified by 4,4 '-methylenedianiline to form a nanocomposite material (GO-amine). Materials were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, derivative thermogravimetric and field emission scanning electron microscopy. The electrochemical behavior of modified carbon paste electrode (CPE) with GO-amine (GO-amine/CPE) was studied by electrochemical methods. The results showed which GO-amine/CPE catalyzes oxygen evolution reaction in alkaline media with an onset potential of 0.4 V (vs. Ag|AgCl|KCl3M), showing a synergistic effect between GO and amine nanocomposite. The high electrochemical stability confirmed the improved electrocatalytic performance of GO-amine. This study affords us a GO-amine based electrocatalyst with high performance and strong durability under alkaline conditions, which can be applied to energy conversion and storage. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：323 / 327

页数：5

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