Formation, powder characterization and sintering of MgCr2O4 by the hydrazine method

被引:0
|
作者
Yoshida, N [1 ]
Takano, Y
Yoshinaka, M
Hirota, K
Yamaguchi, O
机构
[1] Doshisha Univ, Dept Mol Sci & Technol, Kyoto 6100321, Japan
[2] Tanaka Galvanizing Co Ltd, Osaka 5550012, Japan
关键词
D O I
暂无
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Picrochromite (MgCr2O4) crystallizes at 480 degrees to 530 degrees C from an amorphous material prepared by the hydrazine method. The MgCr2O4 powders were characterized for particle size and surface area. Individual particles tend toward a hexagonal morphology above 1000 degrees C. Dense MgCr2O4 ceramics (99.5% of theoretical) with an average grain size of 2 mu m have been fabricated by spark plasma sintering for 5 min at 1400 degrees C and 30 MPa. Their fracture toughness and bending strength are 3.7 MPa.m(1/2) and 310 MPa, respectively.
引用
收藏
页码:2213 / 2215
页数:3
相关论文
共 50 条
  • [41] Catalytic activity of spinel oxides MgCr2O4 and CoCr2O4 for methane combustion
    Hu, Jianan
    Zhao, Wenyan
    Hu, Ruisheng
    Chang, Guiying
    Li, Chun
    Wang, Lingjie
    MATERIALS RESEARCH BULLETIN, 2014, 57 : 268 - 273
  • [42] Spin-Peierls Transition in the Frustrated Spinels ZnCr2O4 and MgCr2O4
    Jaubert, Ludovic D. C.
    Iqbal, Yasir
    Jeschke, Harald O.
    PHYSICAL REVIEW LETTERS, 2025, 134 (08)
  • [43] Energy harvesting using two-dimensional magnesiochromite (MgCr2O4)
    Mahapatra, P. L.
    Singh, A. K.
    Tromer, R.
    Kumbhakar, P.
    Sinha, S. K.
    Lahiri, B.
    Kundu, T. K.
    Galvao, D. S.
    Tiwary, C. S.
    MATERIALS TODAY NANO, 2023, 23
  • [44] Emergence of Highly Degenerate Excited States in the Frustrated Magnet MgCr2O4
    Tomiyasu, K.
    Yokobori, T.
    Kousaka, Y.
    Bewley, R. I.
    Guidi, T.
    Watanabe, T.
    Akimitsu, J.
    Yamada, K.
    PHYSICAL REVIEW LETTERS, 2013, 110 (07)
  • [45] Orientation-dependent stabilization of MgCr2O4 spinel thin films
    Wen, Fangdi
    Liu, Xiaoran
    Kareev, Mikhail
    Wu, Tsung-Chi
    Terilli, Michael
    Chakhalian, Jak
    Shafer, Padraic
    Arenholz, Elke
    PHYSICAL REVIEW B, 2020, 102 (16)
  • [46] THERMAL EXPANSION OF SPINELS MGCR2O4, MGA12O4 AND MGFE2O4
    KAPRALIK, I
    CHEMICKE ZVESTI, 1969, 23 (09): : 665 - &
  • [47] Mechanism of humidity sensing of Ti-doped MgCr2O4 ceramics
    Pingale, SS
    Patil, SF
    Vinod, MP
    Pathak, G
    Vijayamohanan, K
    MATERIALS CHEMISTRY AND PHYSICS, 1996, 46 (01) : 72 - 76
  • [48] Magnetic susceptibility of the frustrated spinels ZnCr2O4, MgCr2O4 and CdCr2O4
    Kant, Ch.
    Deisenhofer, J.
    Tsurkan, V.
    Loidl, A.
    INTERNATIONAL CONFERENCE ON MAGNETISM (ICM 2009), 2010, 200
  • [49] First principles calculations of the formation energy of Cr/Al vacancies in spinel-type MgCr2O4 and MgAl2O4
    Moriwake, H
    Tanaka, I
    Oba, F
    Koyama, Y
    Adachi, H
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2003, 91 (02) : 208 - 210
  • [50] Compressional behavior of MgCr2O4 spinel from first-principles simulation
    ZHANG YanYao
    LIU Xi
    XIONG ZhiHua
    ZHANG ZhiGang
    Science China(Earth Sciences), 2016, 59 (05) : 989 - 996