A stepwise transition from microporosity to mesoporosity in metal-organic frameworks by thermal treatment

被引：83
作者：
Yuan, Daqiang [1 ]
Zhao, Dan [1 ]
Timmons, Daren J. [2 ]
Zhou, Hong-Cai [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[2] Virginia Mil Inst, Dept Chem, Lexington, VA 24450 USA
来源：
CHEMICAL SCIENCE | 2011年 / 2卷 / 01期
关键词：
HYDROGEN STORAGE; SURFACE-AREA; COORDINATION COPOLYMER; CRYSTAL-STRUCTURE; POROUS MATERIALS; CARBON-DIOXIDE; HIGH-CAPACITY; GIANT PORES; POROSITY; MIL-101;
D O I：
10.1039/c0sc00320d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Cd MOF with twisted partially augmented the net was synthesized. Activation at increasing temperatures revealed an unprecedented stepwise transition from microporosity to mesoporosity. This thermal treatment may serve as an alternative approach for the preparation of mesoporous MOFs.
引用
收藏
页码：103 / 106
页数：4
相关论文
共 39 条
[1]   Tailored porous materials [J].
Barton, TJ ;
Bull, LM ;
Klemperer, WG ;
Loy, DA ;
McEnaney, B ;
Misono, M ;
Monson, PA ;
Pez, G ;
Scherer, GW ;
Vartuli, JC ;
Yaghi, OM .
CHEMISTRY OF MATERIALS, 1999, 11 (10) :2633-2656
[2]  
Blatov V. A., 2006, IUCr CompComm Newsletter, V7, P4, DOI DOI 10.1039/B807165A
[3]   Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis [J].
Bux, Helge ;
Liang, Fangyi ;
Li, Yanshuo ;
Cravillon, Janosch ;
Wiebcke, Michael ;
Caro, Juergen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :16000-+
[4]   A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst [J].
Corma, A ;
Díaz-Cabañas, M ;
Martínez-Triguero, J ;
Rey, F ;
Rius, J .
NATURE, 2002, 418 (6897) :514-517
[5]   From microporous to mesoporous molecular sieve materials and their use in catalysis [J].
Corma, A .
CHEMICAL REVIEWS, 1997, 97 (06) :2373-2419
[6]   Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal-Organic Frameworks [J].
Das, Sunirban ;
Kim, Hyunuk ;
Kim, Kimoon .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3814-+
[7]   Ordered porous materials for emerging applications [J].
Davis, ME .
NATURE, 2002, 417 (6891) :813-821
[8]   Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites [J].
Dinca, Mircea ;
Dailly, Anne ;
Liu, Yun ;
Brown, Craig M. ;
Neumann, Dan. A. ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16876-16883
[9]   Mesoporous metal-organic framework with rare etb topology for hydrogen storage and dye assembly [J].
Fang, Qian-Rong ;
Zhu, Guang-Shan ;
Jin, Zhao ;
Ji, Yan-Yan ;
Ye, Jun-Wei ;
Xue, Ming ;
Yang, Hua ;
Wang, Yue ;
Qiu, Shi-Lun .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (35) :6638-6642
[10]   A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F ;
Dutour, J ;
Surblé, S ;
Margiolaki, I .
SCIENCE, 2005, 309 (5743) :2040-2042
1234