Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium

被引：0
|
作者：
Gavrilov, KN
Polosukhin, AI
机构：
[1] SA Esenin Ryazan State Pedag Univ, Ryazan 390000, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia
来源：
USPEKHI KHIMII | 2000年 / 69卷 / 08期
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D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Literature data on the synthesis of rhodium and palladium complexes with optically active P,N-bidentate ligands and their applications in the homogeneous asymmetric catalysis are summarised and discussed. The effect of the nature of the P,N-bidentate compounds on structures of metal complexes and enantioselectivity in catalysis is examined. The allylic substitution, cross-coupling, hydroboration, and hydrosilylation catalysed by Rh or Pd complexes with optically active P,N-bidentate ligands are considered. Prospects for the development in this field of chemistry are demonstrated.
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页码：721 / 743
页数：23
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