Methanol Synthesis from Steel Mill Exhaust Gases: Challenges for the Industrial Cu/ZnO/Al2O3 Catalyst

被引:69
作者
Schittkowski, Julian [1 ]
Ruland, Holger [1 ]
Laudenschleger, Daniel [2 ]
Girod, Kai [3 ]
Kaehler, Kevin [1 ]
Kaluza, Stefan [3 ]
Muhler, Martin [2 ]
Schloegl, Robert [1 ,4 ]
机构
[1] Max Planck Inst Chem Energy Convers, Stiftstr 34-36, D-45470 Mulheim, Germany
[2] Ruhr Univ Bochum, Lab Ind Chem, Univ Str 150, D-44801 Bochum, Germany
[3] Fraunhofer UMSICHT, Osterfelder Str 3, D-46047 Oberhausen, Germany
[4] Fritz Haber Inst, Max Planck Soc, Faradayweg 4-6, D-14195 Berlin, Germany
关键词
Carbon2Chem (R); CO2; recycling; Methanol synthesis; Poisoning; Steel mill exhaust gases; COKE-OVEN GAS; COPPER-BASED CATALYSTS; METAL-SUPPORT INTERACTIONS; CARBON-DIOXIDE; CO2; HYDROGENATION; SHIFT REACTION; BLAST-FURNACE; SUSTAINABLE DEVELOPMENT; RENEWABLE ELECTRICITY; CU/ZNO/ZRO2; CATALYSTS;
D O I
10.1002/cite.201800017
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
One of the major goals of current research on energy conversion is the mitigation of CO2 emission. A beneficial scenario for CO2 utilization is the catalytic conversion of industrial waste or process gases into valuable products. Within the cross-industry approach of Carbon2Chem (R) the synthesis of methanol from steel mill exhaust gases is a promising way to close the carbon cycle based on additional sustainably produced H-2. New catalyst requirements have to be met due to fluctuating feed gas composition and availability as well as gas separation and purification issues.
引用
收藏
页码:1419 / 1429
页数:11
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