Analysis of solids with different matrices by buffer-gas-assisted laser ionization orthogonal time-of-flight mass spectrometry

被引：20

作者：

Yu, Quan ^{[1
]}

Li, Lingfeng ^{[1
]}

Zhu, Eryi ^{[1
]}

Hang, Wei ^{[1
,2
]}

He, Jian ^{[3
]}

Huang, Benli ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, Key Lab Analyt Sci, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

[2] Xiamen Univ, State Key Lab Marine Environm Sci, Xiamen 361005, Peoples R China

[3] Xiamen Univ, Dept Mech & Elect Engn, Xiamen 361005, Peoples R China

来源：

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY | 2010年 / 25卷 / 07期

关键词：

LA-ICP-MS; ELEMENTAL ANALYSIS; ABLATION; PLASMA; IRRADIANCE; NM;

D O I：

10.1039/c000633e

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A laser ionization orthogonal time-of-flight mass spectrometer with a low-pressure source and high laser irradiance was used to analyze 27 solid samples with 9 different matrices, including aluminium, soil, copper sulfide, zinc sulfide, iron, nickel, copper, zinc, and tungsten. The influence of laser energy on non-stoichiometric effects, such as matrix effects and elemental fractionation, has been investigated. The results indicate that matrix effects can be alleviated to a great extent at high laser irradiance. Additionally, with the irradiance of 10(10)-10(11) Wcm(-2), most elements presented relatively stable relative sensitivity coefficients (RSC), while W, Pb, and Bi demonstrated unusual characteristics that their RSCs increased along with increasing laser energy.

引用

页码：1155 / 1158

页数：4

共 29 条

[1] Laser ablation inductively coupled plasma mass spectrometry [J].

Alexander, ML ;

Smith, MR ;

Hartman, JS ;

Mendoza, A ;

Koppenaal, DW .

APPLIED SURFACE SCIENCE, 1998, 127 :255-261

[2] LASER IONIZATION MASS-SPECTROMETRY IN INORGANIC TRACE ANALYSIS [J].

BECKER, JS ;

DIETZE, HJ .

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1992, 344 (03) :69-86

[3] Elemental fractionation effects in high repetition rate IR femtosecond laser ablation ICP-MS analysis of glasses [J].

Claverie, Fanny ;

Fernandez, Beatriz ;

Pecheyran, Christophe ;

Alexis, Joel ;

Donard, Olivier F. X. .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2009, 24 (07) :891-902

[4] Direct analysis of solid samples by fs-LA-ICP-MS [J].

Fernandez, Beatriz ;

Claverie, Fanny ;

Pecheyran, Christophe ;

Donard, Olivier F. X. .

TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2007, 26 (10) :951-966

[5] Elemental fractionation during LA-ICP-MS analysis of silicate glasses: implications for matrix-independent standardization [J].

Gaboardi, Mabry ;

Humayun, Munir .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2009, 24 (09) :1188-1197

[6] Comparison of the ablation behaviour of 266 nm Nd:YAG and 193 nm ArF excimer lasers for LA-ICP-MS analysis [J].

Günther, D ;

Heinrich, CA .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1999, 14 (09) :1369-1374

[7] Solid sample analysis using laser ablation inductively coupled plasma mass spectrometry [J].

Günther, D ;

Hattendorf, B .

TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2005, 24 (03) :255-265

[8] Laser ablation and arc/spark solid sample introduction into inductively coupled plasma mass spectrometers [J].

Günther, D ;

Jackson, SE ;

Longerich, HP .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1999, 54 (3-4) :381-409

[9] Laser-ablation inductively-coupled plasma mass spectrometry [J].

Günther, D .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2002, 372 (01) :31-32

[10] Laser ionization time-of-flight mass spectrometer with an ion guide collision cell for elemental analysis of solids [J].

Hang, W .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2005, 20 (04) :301-307

← 1 2 3 →