Electrochemical lithium doping of a pentacene molecule semiconductor

被引:23
作者
Fang, B [1 ]
Zhou, H [1 ]
Honma, I [1 ]
机构
[1] AIST, Inst Energy Technol, Nanoenergy Mat Grp, Tsukuba, Ibaraki 3058568, Japan
关键词
D O I
10.1063/1.1954873
中图分类号
O59 [应用物理学];
学科分类号
摘要
Li-doped pentacene has been developed by using an electrochemical approach; that is, constant-potential electrolysis. Li-doped pentacene was characterized by Raman spectrometry and x-ray diffraction measurements. Lithium doping introduces a modification of the C-H vibrational modes located at the end of pentacene molecules. A low doping level has been observed for electrochemical synthesis of Li-doped pentacene, and lithium species are supposed to be intercalated between the two-dimensional pentacene layers. The lithium-doped pentacene exhibits a conductivity of similar to 6x10(-3) S cm(-1).
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页码:1 / 3
页数:3
相关论文
共 16 条
[1]   THE STUDY OF LI-GRAPHITE INTERCALATION PROCESSES IN SEVERAL ELECTROLYTE SYSTEMS USING IN-SITU X-RAY-DIFFRACTION [J].
AURBACH, D ;
EINELI, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (06) :1746-1752
[2]   Iodine insertion in pentacene thin films investigated by infrared and Raman spectroscopy [J].
Cazayous, M ;
Sacuto, A ;
Horowitz, G ;
Lang, P ;
Zimmers, A ;
Lobo, RPSM .
PHYSICAL REVIEW B, 2004, 70 (08) :081309-1
[3]   High H2 uptake by alkali-doped carbon nanotubes under ambient pressure and moderate temperatures [J].
Chen, P ;
Wu, X ;
Lin, J ;
Tan, KL .
SCIENCE, 1999, 285 (5424) :91-93
[4]  
COROPCEANU V, 1979, PHYS REV LETT, V42, P1698
[5]   Molecular beam deposited thin films of pentacene for organic field effect transistor applications [J].
Dimitrakopoulos, CD ;
Brown, AR ;
Pomp, A .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (04) :2501-2508
[6]   Resonant Raman scattering in nanoscale pentacene films [J].
He, R ;
Dujovne, I ;
Chen, LW ;
Miao, Q ;
Hirjibehedin, CF ;
Pinczuk, A ;
Nuckolls, C ;
Kloc, C ;
Ron, A .
APPLIED PHYSICS LETTERS, 2004, 84 (06) :987-989
[7]   Efficiency of optical second harmonic generation from pentacene films of different morphology and structure [J].
Jentzsch, T ;
Juepner, HJ ;
Brzezinka, KW ;
Lau, A .
THIN SOLID FILMS, 1998, 315 (1-2) :273-280
[8]   Fabrication of p-pentacene/n-Si organic photodiodes and characterization of their photoelectric properties [J].
Kim, SS ;
Choi, YS ;
Kim, K ;
Kim, JH ;
Im, S .
APPLIED PHYSICS LETTERS, 2003, 82 (04) :639-641
[9]   Hydrogen temperature-programmed desorptions in platinum catalysts: Decomposition and isotopic exchange by spillover hydrogen of chemisorbed ammonia [J].
Miller, JT ;
Meyers, BL ;
Barr, MK ;
Modica, FS ;
Koningsberger, DC .
JOURNAL OF CATALYSIS, 1996, 159 (01) :41-49
[10]   HIGHLY ORDERED AND CONDUCTING THIN-FILM OF PENTACENE DOPED WITH IODINE VAPOR [J].
MINAKATA, T ;
NAGOYA, I ;
OZAKI, M .
JOURNAL OF APPLIED PHYSICS, 1991, 69 (10) :7354-7356