Vanillin Acrylate-Based Resins for Optical 3D Printing

被引:25
|
作者
Navaruckiene, Aukse [1 ]
Skliutas, Edvinas [2 ]
Kasetaite, Sigita [1 ]
Rekstyte, Sima [2 ]
Raudoniene, Vita [3 ]
Bridziuviene, Danguole [3 ]
Malinauskas, Mangirdas [2 ]
Ostrauskaite, Jolita [1 ]
机构
[1] Kaunas Univ Technol, Dept Polymer Chem & Technol, Radvilenu Rd 19, LT-50254 Kaunas, Lithuania
[2] Vilnius Univ, Fac Phys, Laser Res Ctr, Sauletekis Ave 10, LT-10223 Vilnius, Lithuania
[3] Nat Res Ctr, Biodeteriorat Res Lab, Akad Str 2, LT-08412 Vilnius, Lithuania
基金
欧盟地平线“2020”;
关键词
vanillin dimethacrylate; vanillin diacrylate; photopolymerization; optical 3D printing; direct laser writing; replica molding; PHOTOINITIATED POLYMERIZATION; PHOTOPOLYMERIZATION;
D O I
10.3390/polym12020397
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The investigation of biobased systems as photocurable resins for optical 3D printing has attracted great attention in recent years; therefore, novel vanillin acrylate-based resins were designed and investigated. Cross-linked polymers were prepared by radical photopolymerization of vanillin derivatives (vanillin dimethacrylate and vanillin diacrylate) using ethyl(2,4,6-trimethylbenzoyl)phenylphosphinate as photoinitiator. The changes of rheological properties were examined during the curing with ultraviolet/visible irradiation to detect the influences of solvent, photoinitiator, and vanillin derivative on cross-linking rate and network formation. Vanillin diacrylate-based polymers had higher values of yield of insoluble fraction, thermal stability, and better mechanical properties in comparison to vanillin dimethacrylate-based polymers. Moreover, the vanillin diacrylate polymer film showed a significant antimicrobial effect, only a bit weaker than that of chitosan film. Thermal and mechanical properties of vanillin acrylate-based polymers were comparable with those of commercial petroleum-derived materials used in optical 3D printing. Also, vanillin diacrylate proved to be well-suited for optical printing as was demonstrated by employing direct laser writing 3D lithography and microtransfer molding techniques.
引用
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页数:14
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