NiFe layered double hydroxide nanosheet array for high-efficiency electrocatalytic reduction of nitric oxide to ammonia

被引：94

作者：

Meng, Ge ^{[1
]}

Wei, Tianran ^{[2
]}

Liu, Weijia ^{[2
]}

Li, Wenbo ^{[2
]}

Zhang, Shusheng ^{[3
]}

Liu, Wenxian ^{[4
]}

Liu, Qian ^{[5
]}

Bao, Haihong ^{[6
]}

Luo, Jun ^{[7
]}

Liu, Xijun ^{[2
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Key Lab Carbon Mat Zhejiang Prov, Wenzhou 325035, Peoples R China

[2] Guangxi Univ, Sch Resource Envimnments & Mat, MOE Key Lab New Proc Technol Nonferrous Met & Mat, Nanning 530004, Peoples R China

[3] Zhengzhou Univ, Coll Chem, Zhengzhou 450000, Peoples R China

[4] Zhejiang Univ Technol, Coll Mat Sci & Engn, Hangzhou 310014, Peoples R China

[5] Chengdu Univ, Inst Adv Study, Chengdu 610106, Sichuan, Peoples R China

[6] Tianjin Univ Sci & Technol, Sch Chem Engn & Mat, Tianjin 300457, Peoples R China

[7] Tianjin Univ Technol, Sch Mat Sci & Engn, Inst New Energy Mat & Low Carbon Technol, Tianjin 300384, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 58期

基金：

中国国家自然科学基金;

关键词：

NITROGEN-FIXATION; N-2; FE;

D O I：

10.1039/d2cc02463b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here, we demonstrate that under ambient conditions, a nickel-iron layered double hydroxide nanosheet array can exhibit a promising NORR performance, delivering a maximal faradaic efficiency of 82% and a corresponding yield rate of 112 mu mol h(-1) cm(-2), along with high stability for over 30 h. This superior performance is further confirmed as a proof-of-concept for a Zn-NO battery, in which a peak power density of 1.8 mW cm(-2) and a large NH3 yield rate of 32 mu mol h(-1) cm(-2) are observed. Theoretical analyses indicate that NiFe-LDH exhibits effective NO activation capacity and slow hydrogen evolution kinetics.

引用

页码：8097 / 8100

页数：4

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