Light olefin synthesis from a diversity of renewable and fossil feedstocks: state-of the-art and outlook

被引:138
作者
Chernyak, Sergei A. [1 ]
Corda, Massimo [1 ]
Dath, Jean-Pierre [2 ]
Ordomsky, Vitaly V. [1 ]
Khodakov, Andrei Y. [1 ]
机构
[1] Univ Lille, Univ Artois, CNRS,UCCS Unite Catalyse & Chim Solide, Cent Lille,UMR 8181, Lille, France
[2] TotalEnergies SE, Direct Rech & Dev, TotalEnergies Tech Belgium 1, Zane Ind Feluy C, B-7181 Seneffe, Belgium
基金
欧盟地平线“2020”;
关键词
FISCHER-TROPSCH SYNTHESIS; CATALYTIC FAST PYROLYSIS; SUPPORTED IRON CATALYSTS; METHANOL-TO-HYDROCARBONS; SELECTIVE OXIDATIVE DEHYDROGENATION; CO2; HYDROGENATION; PROPANE DEHYDROGENATION; CARBON-DIOXIDE; IN-SITU; OXIDE CATALYSTS;
D O I
10.1039/d1cs01036k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Light olefins are important feedstocks and platform molecules for the chemical industry. Their synthesis has been a research priority in both academia and industry. There are many different approaches to the synthesis of these compounds, which differ by the choice of raw materials, catalysts and reaction conditions. The goals of this review are to highlight the most recent trends in light olefin synthesis and to perform a comparative analysis of different synthetic routes using several quantitative characteristics: selectivity, productivity, severity of operating conditions, stability, technological maturity and sustainability. Traditionally, on an industrial scale, the cracking of oil fractions has been used to produce light olefins. Methanol-to-olefins, alkane direct or oxidative dehydrogenation technologies have great potential in the short term and have already reached scientific and technological maturities. Major progress should be made in the field of methanol-mediated CO and CO2 direct hydrogenation to light olefins. The electrocatalytic reduction of CO2 to light olefins is a very attractive process in the long run due to the low reaction temperature and possible use of sustainable electricity. The application of modern concepts such as electricity-driven process intensification, looping, CO2 management and nanoscale catalyst design should lead in the near future to more environmentally friendly, energy efficient and selective large-scale technologies for light olefin synthesis.
引用
收藏
页码:7994 / 8044
页数:51
相关论文
共 464 条
[1]   Iron catalyst supported on carbon nanotubes for Fischer-Tropsch synthesis: Effects of Mo promotion [J].
Abbaslou, Reza M. Malek ;
Soltan, Jafar ;
Dalai, Ajay K. .
FUEL, 2011, 90 (03) :1139-1144
[2]   EFFECTS OF SODIUM, ALUMINUM AND MANGANESE ON THE FISCHER-TROPSCH SYNTHESIS OVER ALUMINA-SUPPORTED IRON CATALYSTS [J].
ABBOT, J ;
CLARK, NJ ;
BAKER, BG .
APPLIED CATALYSIS, 1986, 26 (1-2) :141-153
[3]  
Abdelbaki Y., 2021, APPL CATAL A-GEN, V623, P1, DOI DOI 10.1016/J.APCATA.2021.118242
[4]   Maximization of FCC light olefins by high severity operation and ZSM-5 addition [J].
Aitani, A ;
Yoshikawa, T ;
Ino, T .
CATALYSIS TODAY, 2000, 60 (1-2) :111-117
[5]   An Overview of Light Olefins Production via Steam Enhanced Catalytic Cracking [J].
Akah, Aaron ;
Williams, Jesse ;
Ghrami, Musaed .
CATALYSIS SURVEYS FROM ASIA, 2019, 23 (04) :265-276
[6]   Maximizing propylene production via FCC technology [J].
Akah, Aaron ;
Al-Ghrami, Musaed .
APPLIED PETROCHEMICAL RESEARCH, 2015, 5 (04) :377-392
[7]   A green and cost-effective surfactant-assisted synthesis of SAPO-34 using dual microporous templates with improved performance in MTO reaction [J].
Akhgar, Sahar ;
Towfighi, Jafar ;
Hamidzadeh, Marzieh .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2020, 95 (02) :253-264
[8]   Catalytic Cracking of Light Crude Oil to Light Olefins and Naphtha over E-Cat and MFI: Microactivity Test versus Advanced Cracking Evaluation and the Effect of High Reaction Temperature [J].
Al-Khattaf, Sulaiman ;
Saeed, Mian Rahat ;
Aitani, Abdullah ;
Klein, Michael T. .
ENERGY & FUELS, 2018, 32 (05) :6189-6199
[9]   Oxidative dehydrogenation of ethane to ethylene in an integrated CO2 capture-utilization process [J].
Al-Mamoori, Ahmed ;
Lawson, Shane ;
Rownaghi, Ali A. ;
Rezaei, Fateme .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 278
[10]   Recycling and recovery routes of plastic solid waste (PSW): A review [J].
Al-Salem, S. M. ;
Lettieri, P. ;
Baeyens, J. .
WASTE MANAGEMENT, 2009, 29 (10) :2625-2643