Synthesis and characterization of three Cu(II), Zn(II), Cd(II) supramolecular complexes bridged by biphenyl 2,2′-dicarboxylate

被引：6
|
作者：
Ashiry, Kother Osman [1 ]
Zhao, Ya-Hui [1 ]
Shao, Kui-Zhan [1 ]
Su, Zhong Min [1 ]
Fu, Yao-Mei [1 ]
Hao, Xiang-Rong [1 ]
Wang, Yong [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Inst Funct Mat Chem, Changchun 130024, Peoples R China
来源：
SOLID STATE SCIENCES | 2007年 / 9卷 / 11期
基金：
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词：
1,1 '-biphenyl-2,2 '-dicarboxylic acid; hydrothermal synthesis; supramolecular network; fluorescence;
D O I：
10.1016/j.solidstatesciences.2007.07.028
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three complexes, M-2(bpy)(2)(bpdc)(2)center dot xH(2)O [M = Cu, x = 0; M = Zn or Cd, x = 2], have been hydrothermally synthesized by 1,1 '-biphenyl-2,2 '-dicarboxylic acid (H(2)bpdc) with 2,2 '-bipyridine (bpy) to form binuclear molecules. In each, the two bpdc groups align the two opposing planar [M(bpy)](2+) cations. The molecules are connected by C-H center dot center dot center dot O hydrogen bonds, pi-pi stacking, and C-H center dot center dot center dot pi interactions to form three dimensional supramolecular networks. Furthermore, at room temperature, complex 3 exhibits strong photoluminescence. (C) 2007 Published by Elsevier Masson SAS.
引用
收藏
页码：1006 / 1011
页数：6
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