3-Hydroxy-2-[(4-hydroxy-3,5-dimethoxyphenyl)(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one

被引:3
作者
Yang, Xiao-Hui [1 ]
Zhou, Yong-Hong [1 ]
Zhang, Meng [1 ]
Hu, Li-Hong [1 ]
机构
[1] Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
D O I
10.1107/S1600536811002698
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C25H32O7, the 3-hydroxy-5,5-dimethylcyclohex-2-enone rings adopt slightly distorted envelope conformations with the two planes at the base of the envelope forming dihedral angles of 57.6 ( 4) and 53.9 (9)degrees with the benzene ring. There is an intramolecular hydroxy-ketone O-H center dot center dot center dot O interaction between the two substituted cyclohexane rings as well as a short intramolecular phenol-methoxy O-H center dot center dot center dot O interaction.
引用
收藏
页码:O492 / U1743
页数:11
相关论文
共 9 条
[1]  
Davies D. T., 2005, US Patent, Patent No. 6911442
[2]  
Enraf-Nonius, 1994, CAD 4 EXPRESS
[3]  
Harms K., 1996, XCAD4
[4]   A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].
NORTH, ACT ;
PHILLIPS, DC ;
MATHEWS, FS .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&
[5]   SYNTHESIS, CONFIGURATION, AND CALCIUM MODULATORY PROPERTIES OF ENANTIOMERICALLY PURE 5-OXO-1,4,5,6,7,8-HEXAHYDROQUINOLINE-3-CARBOXYLATES [J].
ROSE, U ;
DRAGER, M .
JOURNAL OF MEDICINAL CHEMISTRY, 1992, 35 (12) :2238-2243
[6]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[7]   9-(4-Hydroxy-3-methyoxyphenyl)-3,3,6,6,10-pentamethyl-1,2,3,4,5,6,7,8,9,10-decahydroacridine-1,8-dione [J].
Tu, SJ ;
Zhang, XJ ;
Zhu, SL .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 :O1870-O1872
[8]  
Warrior P., 2005, WO Patent, Patent No. 2005060748
[9]   Aqua(2-oxido-2,2-diphenylacetato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) [J].
Yang, Xiao-Xia ;
Zhang, Fu-Yong ;
Xu, Shi-Hai .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M69-U745