Functionalization of nano-cellulose by coupling agent with green strategy

被引:10
作者
Xu, Chang-An [1 ,2 ]
Lu, Mangeng [1 ,2 ,3 ]
Wu, Kun [1 ,2 ,4 ]
Shi, Jun [1 ,2 ,5 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Guangdong Prov Key Lab Organ Polymer Mat Elect, Guangzhou 510650, Peoples R China
[4] CAS Engn Lab Special Fine Chem, Guangzhou 510650, Peoples R China
[5] Cash GCC Shaoguan Res Inst Adv Mat, Shaoguan 512026, Peoples R China
关键词
Green method; Nano-cellulose; Coupling agent; NANOCELLULOSE; OXIDATION; FIBERS;
D O I
10.1016/j.inoche.2021.108939
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nano-cellulose is widely used in the fields of double-hydrophobic interface fabric, high-grade protective clothing, chemical industry and medicine. Although the research of nano-cellulose has received widespread attention, because of its strong intermolecular force, its dispersion in the medium is not ideal. In order to further increase the dispersion of nano-cellulose in the medium, one of the methods used is to weaken the hydrogen bonding between nano-cellulose by chemical route. In this work, nano-cellulose is simply modified by coupling agent in environment-friendly solvent. Different analytical methods are used to verify the successful modification of nano -cellulose. The results show that the dispersibility of the modified nano-cellulose in water is improved, and the thermal stability is enhanced in the range of 300-567celcius. It is worth remarking that the transmittance of the modified nano-cellulose in visible light still remains above 85%. This study provides a feasible, simple and environmental-friendly strategy for developing the application of nano-cellulose, especially in the field of pho-topolymerization, radical polymerization and cross linking reaction.
引用
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页数:7
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