A self-sacrifice template strategy to synthesize Co-LDH/MXene for lithium-ion batteries

被引:40
作者
Li, Chenyang [1 ]
Dai, Zhiqiang [1 ]
Liu, Wei [1 ]
Kantichaimongkol, Pongsakorn [2 ,3 ]
Yu, Pengfei [1 ]
Pattananuwat, Prasit [4 ,5 ]
Qin, Jiaqian [3 ,5 ]
Zhang, Xinyu [1 ]
机构
[1] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Hebei, Peoples R China
[2] Chulalongkorn Univ, Int Grad Program Nanosci & Technol, Bangkok 10330, Thailand
[3] Chulalongkorn Univ, Met & Mat Sci Res Inst, Bangkok 10330, Thailand
[4] Chulalongkorn Univ, Fac Sci, Dept Mat Sci, Bangkok 10330, Thailand
[5] Chulalongkorn Univ, Res Unit Adv Mat Energy Storage, Bangkok 10330, Thailand
关键词
LAYERED DOUBLE HYDROXIDES; ELECTROCATALYSTS; NANOSHEET; COMPOSITE; CAPACITY; ANODE;
D O I
10.1039/d1cc04492c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To overcome the limitations of both LDHs and MXenes, we develop a self-sacrifice template strategy using a zeolite imidazolate framework-67 (ZIF-67) to derive Co-LDH anchored on an MXene conductive substrate (Co-LDH/MXene). In this process, ZIF-67 grows on the MXene nanosheets, then spontaneously transforms into Co-LDH/MXene in aqueous solution at room temperature. As the LIB anode, it shows a reversible capacity of 854.9 and 398.0 mAh g(-1) at 0.1 and 1 A g(-1), respectively. This work proposes a feasible synthesis method for the in situ construction of a Co-LDH/MXene hybrid, which may be suitable for other MXenes.
引用
收藏
页码:11378 / 11381
页数:4
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