Controlled radical polymerization in the presence of N-oxyls

被引：0
作者：
Brinkmann-Rengel, S [1 ]
Sutoris, HF [1 ]
Weiss, H [1 ]
机构：
[1] BASF AG, D-67056 Ludwigshafen, Germany
来源：
MACROMOLECULAR SYMPOSIA | 2001年 / 163卷
关键词：
D O I：
10.1002/1521-3900(200101)163:1<145::AID-MASY145>3.0.CO;2-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Recent development in controlled radical polymerization has provided a tool to combine a relatively robust radical polymerization technique with structural control. This contribution focuses on stable free radical polymerization in the presence of nitroxides. The influence of 2,2,6,6-tetramethyl-piperidine-N-oxyl (TEMPO) and temperature on the copolymerization of styrene and acrylonitrile will be discussed. In the second part a new class of nitroxide stable free radicals will be presented that shows enhanced performance in styrene polymerizations.
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页码：145 / 156
页数：12
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