Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts

被引：24

作者：

Moussa, Mehdi Elsayed ^{[1
]}

Fleischmann, Martin ^{[1
]}

Peresypkina, Eugenia V. ^{[1
,2
,3
]}

Duetsch, Luis ^{[1
]}

Seidl, Michael ^{[1
]}

Balazs, Gabor ^{[1
]}

Scheer, Manfred ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

[2] RAS, Nikolaev Inst Inorgan Chem, Siberian Div, Acad Lavrentyev Str 3, Novosibirsk 630090, Russia

[3] Novosibirsk State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 25期

基金：

欧洲研究理事会;

关键词：

Phosphorus; Coordination polymers; Coordinating anions; Silver; Synthetic methods; ORGANIC HYBRID MATERIALS; ONE-DIMENSIONAL POLYMERS; LIGAND COMPLEXES; NMR-SPECTROSCOPY; BUILDING-BLOCKS; PENTAPHOSPHAFERROCENE; FRAMEWORKS; CHEMISTRY; MOLECULE; BEHAVIOR;

D O I：

10.1002/ejic.201700646

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)(4)(eta(2)-P-2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)(3)}(4)] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}(3)] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag-2(eta(2)-1)(2)(eta(1):eta(1)-1)(2)][TEF](2) (2) dimer and the [Ag-2(eta(1):eta(1)-1)(3)](n)[TEF](2n) (3) coordination polymer, whereas the second reaction afforded the [Ag-2(eta(1):eta(1)-1)(2)(eta(1)-CH2Cl2)(2)(eta(2)-C7H8)(2)][FAl](2) (4) or the [Ag-2(eta(2)-1)(2)(eta(1):eta(1)-1)(2)][FAl](2) (5) dimer and the [Ag-2(eta(1):eta(1)-1)(4)](n)[FAl](2n) (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/ or the synthetic procedure.

引用

页码：3222 / 3226

页数：5