Statistical effects in the model of solvent extraction of metal complexes with neutral ligands

被引：0

作者：

Kopkowski, A ^{[1
]}

Rauckyte, T ^{[1
]}

Ojczenasz, P ^{[1
]}

机构：

[1] Univ Technol & Agr, Dept Chem Engn & Technol, PL-85326 Bydgoszcz, Poland

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 2006年 / 24卷 / 01期

关键词：

metal complexes; extraction of metal ions; stability constants; partition constants; statistical effects;

D O I：

10.1080/07366290500388533

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new model of solvent extraction of metal complexes with neutral ligands is presented. It was based on Bjerrum's concept of statistical effects in stability constants. This model required the minimum set of parameters describing a given extraction system. The usability of the model to evaluate the individual equilibrium constants related to both the aqueous and the organic phase was shown on the experimental example of nickel(II) nitrate complexes with N-propylimidazole ligands, extracted from water to dichloromethane.

引用

页码：57 / 64

页数：8