Ytterbium-Doped ZnO Flowers Based Phenyl Hydrazine Chemical Sensor

被引:11
作者
Al-Hadeethi, Yas [1 ,2 ]
Umar, Ahmad [3 ,4 ]
Singh, Kulvinder [5 ]
Ibrahim, Ahmed A. [3 ,4 ]
Al-Heniti, Saleh. H. [1 ,2 ]
Raffah, Bahaaudin M. [1 ,2 ]
机构
[1] King Abdulaziz Univ, Dept Phys, Fac Sci, Jeddah 21589, Saudi Arabia
[2] King Abdulaziz Univ, Lithog Devices Fabricat & Dev Res Grp, Deanship Sci Res, Jeddah 21589, Saudi Arabia
[3] Najran Univ, Dept Chem, Fac Sci & Arts, POB 1988, Najran 11001, Saudi Arabia
[4] Najran Univ, PCSED, POB 1988, Najran 11001, Saudi Arabia
[5] Maharaja Agrasen Univ, Dept Chem, Sch Basic & Appl Sci, Baddi 174103, India
关键词
Yb-Doped ZnO; Chemical Sensor; Phenyl Hydrazine; GAS-SENSING PROPERTIES; MODIFIED ELECTRODE; NANOCOMPOSITE; NANOPARTICLES; NANOSTRUCTURES; DEGRADATION; MORPHOLOGY; GROWTH; DYE;
D O I
10.1166/jnn.2019.16283
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, we report the fabrication and characterization of phenyl hydrazine sensor based on ytterbium (Yb) doped ZnO flowers composed of nanorods prepared by simple hydrothermal process. The as-synthesized nanomaterial was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) attached with energy dispersive spectroscopy (EDS), Fourier transformation infrared (FTIR) and Raman-scattering spectroscopy which revealed the large-quantity synthesis, well-crystallinity and wurtzite hexagonal crystal structure of Yb-doped ZnO flowers. The fabricated phenyl hydrazine chemical sensor, by employing Yb-doped ZnO flowers as an electron mediator, exhibited sensitivity of similar to 34.2 mu A.mM(-1).cm(-2), detection limit of 24 mM and linear dynamic range of 0.25-4.0 mM. The presented work demonstrates that the Yb-doped ZnO nanomaterials are promising electron mediator which can be used for the fabrication of chemical sensors to detect various hazardous and toxic chemicals as phenyl hydrazine.
引用
收藏
页码:4199 / 4204
页数:6
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