Development of more labile low electron count Co(I) sources: mild, catalytic functionalization of activated alkanes using a [(Cp*Co)2-μ-(η4:η4-arene)] complex

被引：30

作者：

Hung-Low, Fernando ^{[1
]}

Krogman, Jeremy P. ^{[1
]}

Tye, Jesse W. ^{[2
]}

Bradley, Christopher A. ^{[1
]}

机构：

[1] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA

[2] Ball State Univ, Dept Chem, Muncie, IN 47306 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 03期

关键词：

TRIPLE-DECKER; EXCHANGE-REACTIONS; H/D EXCHANGE; REACTIVITY; COBALT(I); ARENE; CONVERSION; LIGANDS; BONDS;

D O I：

10.1039/c1cc15458c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic transfer dehydrogenation of silyl protected amines, requiring sp(3) C-H bond activation, is mediated by a bridging arene complex of the type [(Cp*Co)(2)-mu-(eta(4):eta(4)-arene)] under mild conditions. Mechanistic and qualitative rate studies establish the compound as a more reactive Co(I) source when compared to other known Cp*Co(I) complexes.

引用

页码：368 / 370

页数：3

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