Synthesis and characterization of polynuclear lanthanide aryloxides

被引：13
作者：
Carretas, J
Branco, J
Marçalo, J
Isolani, P
Domingos, A
de Matos, AP
机构：
[1] ITN, Dept Quim, P-2686953 Sacavem, Portugal
[2] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2001年 / 323卷
关键词：
europium; ytterbium; aryloxides;
D O I：
10.1016/S0925-8388(01)01122-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reactions of europium and ytterbium in liquid ammonia with a solution of I-naphthol in tetrahydrofuran provide a convenient route to lanthanide aryloxides. The polymetallic lanthanide complexes [Eu-4(mu -OC10H7)(6)(OC10H7)(2)(THF)(10)].2THF 1 and [Yb(mu -OC10H7)-(OC10H7)(2)(THF)(MeCN)](2).2MeCN 2 were synthesized and characterized by X-ray diffraction studies. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：169 / 172
页数：4
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