Synthesis and characterization of polynuclear lanthanide aryloxides

被引：13

作者：

Carretas, J

Branco, J

Marçalo, J

Isolani, P

Domingos, A

de Matos, AP

机构：

[1] ITN, Dept Quim, P-2686953 Sacavem, Portugal

[2] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2001年 / 323卷

关键词：

europium; ytterbium; aryloxides;

D O I：

10.1016/S0925-8388(01)01122-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of europium and ytterbium in liquid ammonia with a solution of I-naphthol in tetrahydrofuran provide a convenient route to lanthanide aryloxides. The polymetallic lanthanide complexes [Eu-4(mu -OC10H7)(6)(OC10H7)(2)(THF)(10)].2THF 1 and [Yb(mu -OC10H7)-(OC10H7)(2)(THF)(MeCN)](2).2MeCN 2 were synthesized and characterized by X-ray diffraction studies. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：169 / 172

页数：4

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