Synthesis and structure of organically templated lanthanum sulfate [C4N3H16][La(SO4)3]•H2O

被引：65
|
作者：
Xing, Y [1 ]
Liu, YL [1 ]
Shi, Z [1 ]
Meng, H [1 ]
Pang, WQ [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2003年 / 174卷 / 02期
关键词：
hydrothermal methods; lanthanum sulfate; diethylenetriamine; chain;
D O I：
10.1016/S0022-4596(03)00255-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first organically templated one-dimensional lanthanum sulfate [C4N3H16][La(SO4)(3)] . H2O has been prepared employing hydrothermal methods in the presence of diethylenetriamine (DETA). The structure was determined by single-crystal X-ray diffraction (XRD). The title compound crystallizes in the triclinic system, space group P-1 (No.2) with cell parameters M = 551.30 a = 8.2773(7) Angstrom, b = 9.5660(6) Angstrom, c = 10.4363(6) Angstrom, alpha = 105.661(2)degrees, beta = 102.849(3)degrees, gamma = 104.376(3)degrees, V = 732.72(9) Angstrom(3). Z = 2 R = 0.0285, wR = 0.0778. The structure consists of infinite linear chains. The chains are held together by hydrogen bond interactions involving the hydrogens of the amine and the framework oxygens. The as-synthesized product is characterized by powder XRD, inductive couple plasma analysis and thermogravimetric analysis. (C) 2003 Elsevier Inc. All rights reserved.
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收藏
页码：381 / 385
页数：5
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