Targeted synthesis of a large triazine-based [4+6] organic molecular cage: structure, porosity and gas separation

被引：83

作者：

Ding, Huimin ^{[1
]}

Yang, Yihui ^{[1
]}

Li, Bijian ^{[1
]}

Pan, Feng ^{[1
]}

Zhu, Guozhu ^{[1
]}

Zeller, Matthias ^{[3
]}

Yuan, Daqiang ^{[2
]}

Wang, Cheng ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 10期

关键词：

SHAPE PERSISTENCE; ROOM-TEMPERATURE; POROUS MATERIALS; SURFACE-AREA; FRAMEWORKS; CHEMISTRY; WATER; CONDENSATION; SELECTIVITY; ADSORPTION;

D O I：

10.1039/c4cc08883b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report the targeted synthesis and solid state assembly of a novel triazine-based [4 + 6] organic molecular cage. The tetrahedral cage features a large cavity ( similar to 2070 angstrom(3)), and after desolvation, the resultant material exhibits a high Brunauer-Emmett-Teller surface area of 1181 m(2) g(-1) and also features selective adsorption of CO2 over N-2.

引用

页码：1976 / 1979

页数：4

共 48 条

[1] Molecular Marriage through Partner Preferences in Covalent Cage Formation and Cage-to-Cage Transformation [J].

Acharyya, Koushik ;

Mukherjee, Sandip ;

Mukherjee, Partha Sarathi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (02) :554-557

[2]

[Anonymous], 2014, ANGEW CHEM

[3] Kinetically Controlled Porosity in a Robust Organic Cage Material [J].

Avellaneda, Antonio ;

Valente, Peter ;

Burgun, Alexandre ;

Evans, Jack D. ;

Markwell-Heys, Adrian W. ;

Rankine, Damien ;

Nielsen, David J. ;

Hill, Matthew R. ;

Sumby, Christopher J. ;

Doonan, Christian J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (13) :3746-3749

[4] Dynamic imine chemistry [J].

Belowich, Matthew E. ;

Stoddart, J. Fraser .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (06) :2003-2024

[5] Supramolecular Engineering of Intrinsic and Extrinsic Porosity in Covalent Organic Cages [J].

Bojdys, Michael J. ;

Briggs, Michael E. ;

Jones, James T. A. ;

Adams, Dave J. ;

Chong, Samantha Y. ;

Schmidtmann, Marc ;

Cooper, Andrew I. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (41) :16566-16571

[6] Shape Prediction for Supramolecular Organic Nanostructures: [4+4] Macrocyclic Tetrapods [J].

Briggs, Michael E. ;

Jells, Kim E. ;

Chong, Samantha Y. ;

Lester, Catherine ;

Schmidtmann, Marc ;

Adams, Dave J. ;

Cooper, Andrew I. .

CRYSTAL GROWTH & DESIGN, 2013, 13 (11) :4993-5000

[7] Highly-efficient synthesis of covalent porphyrinic cages via DABCO-templated imine condensation reactions [J].

Ding, Huimin ;

Meng, Xiangshi ;

Cui, Xu ;

Yang, Yihui ;

Zhou, Tailin ;

Wang, Caixing ;

Zeller, Matthias ;

Wang, Cheng .

CHEMICAL COMMUNICATIONS, 2014, 50 (76) :11162-11164

[8] The Chemistry and Applications of Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Cordova, Kyle E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2013, 341 (6149) :974-+

[9] [1,3,5]-triazine: A versatile heterocycle in current applications of organic chemistry [J].

Giacomelli, G ;

Porcheddu, A ;

De Luca, L .

CURRENT ORGANIC CHEMISTRY, 2004, 8 (15) :1497-1519

[10]

Hof F, 2002, ANGEW CHEM INT EDIT, V41, P1488, DOI 10.1002/1521-3773(20020503)41:9<1488::AID-ANIE1488>3.0.CO

← 1 2 3 4 5 →