Targeted synthesis of a large triazine-based [4+6] organic molecular cage: structure, porosity and gas separation

被引：81

作者：

Ding, Huimin ^{[1
]}

Yang, Yihui ^{[1
]}

Li, Bijian ^{[1
]}

Pan, Feng ^{[1
]}

Zhu, Guozhu ^{[1
]}

Zeller, Matthias ^{[3
]}

Yuan, Daqiang ^{[2
]}

Wang, Cheng ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 10期

关键词：

SHAPE PERSISTENCE; ROOM-TEMPERATURE; POROUS MATERIALS; SURFACE-AREA; FRAMEWORKS; CHEMISTRY; WATER; CONDENSATION; SELECTIVITY; ADSORPTION;

D O I：

10.1039/c4cc08883b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report the targeted synthesis and solid state assembly of a novel triazine-based [4 + 6] organic molecular cage. The tetrahedral cage features a large cavity ( similar to 2070 angstrom(3)), and after desolvation, the resultant material exhibits a high Brunauer-Emmett-Teller surface area of 1181 m(2) g(-1) and also features selective adsorption of CO2 over N-2.

引用

页码：1976 / 1979

页数：4

共 48 条

[1] Molecular Marriage through Partner Preferences in Covalent Cage Formation and Cage-to-Cage Transformation
Acharyya, Koushik
Mukherjee, Sandip
Mukherjee, Partha Sarathi
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (02) : 554 - 557
[2] [Anonymous], 2014, ANGEW CHEM
[3] Kinetically Controlled Porosity in a Robust Organic Cage Material
Avellaneda, Antonio
Valente, Peter
Burgun, Alexandre
Evans, Jack D.
Markwell-Heys, Adrian W.
Rankine, Damien
Nielsen, David J.
Hill, Matthew R.
Sumby, Christopher J.
Doonan, Christian J.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (13) : 3746 - 3749
[4] Dynamic imine chemistry
Belowich, Matthew E.
Stoddart, J. Fraser
[J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (06) : 2003 - 2024
[5] Supramolecular Engineering of Intrinsic and Extrinsic Porosity in Covalent Organic Cages
Bojdys, Michael J.
Briggs, Michael E.
Jones, James T. A.
Adams, Dave J.
Chong, Samantha Y.
Schmidtmann, Marc
Cooper, Andrew I.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (41) : 16566 - 16571
[6] Shape Prediction for Supramolecular Organic Nanostructures: [4+4] Macrocyclic Tetrapods
Briggs, Michael E.
Jells, Kim E.
Chong, Samantha Y.
Lester, Catherine
Schmidtmann, Marc
Adams, Dave J.
Cooper, Andrew I.
[J]. CRYSTAL GROWTH & DESIGN, 2013, 13 (11) : 4993 - 5000
[7] Highly-efficient synthesis of covalent porphyrinic cages via DABCO-templated imine condensation reactions
Ding, Huimin
Meng, Xiangshi
Cui, Xu
Yang, Yihui
Zhou, Tailin
Wang, Caixing
Zeller, Matthias
Wang, Cheng
[J]. CHEMICAL COMMUNICATIONS, 2014, 50 (76) : 11162 - 11164
[8] The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, Hiroyasu
Cordova, Kyle E.
O'Keeffe, Michael
Yaghi, Omar M.
[J]. SCIENCE, 2013, 341 (6149) : 974 - +
[9] [1,3,5]-triazine: A versatile heterocycle in current applications of organic chemistry
Giacomelli, G
Porcheddu, A
De Luca, L
[J]. CURRENT ORGANIC CHEMISTRY, 2004, 8 (15) : 1497 - 1519
[10] Hof F, 2002, ANGEW CHEM INT EDIT, V41, P1488, DOI 10.1002/1521-3773(20020503)41:9<1488::AID-ANIE1488>3.0.CO

← 1 2 3 4 5 →