Fabrication of starch-based nanospheres to stabilize pickering emulsion

被引:163
作者
Tan, Ying [1 ]
Xu, Kun [1 ]
Liu, Chang [1 ,2 ]
Li, Yangling [1 ,2 ]
Lua, Cuige [1 ,2 ]
Wang, Pixin [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Ecomat Polymers, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
Pickering emulsion; Starch; Nanospheres; pH-responsive; Amphiphilic; PHASE INVERSION; CORN STARCH; COLLOIDOSOMES; EMULSIFIERS; PARTICLES; FOAMS; WATER;
D O I
10.1016/j.carbpol.2012.02.018
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Starch is successively modified by acetic anhydride and phthalic anhydride, and then starch-based nanospheres are fabricated by a simple nanoprecipitation procedure. These pH-responsive amphiphilic starch-based nanospheres of uniform size are used as particulate emulsifiers to stabilize Pickering emulsions. CLSM and SEM characterization find that starch-based nanospheres adsorbed at the interface between oil phase and water phase. Moreover, the catastrophic inversion and transitional inversion of such emulsions can be easily achieved by varied the water/oil volume ratio and pH of aqueous dispersion, respectively. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:1358 / 1363
页数:6
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