Hypervalent Iodine(III)-LiX Combination in Fluoroalcohol Solvent for Aromatic Halogenation of Electron-Rich Arenecarboxylic Acids

被引：38

作者：

Hamamoto, Hiromi ^{[1
]}

Hattori, Sho ^{[1
]}

Takemaru, Kaori ^{[1
]}

Miki, Yasuyoshi ^{[1
]}

机构：

[1] Kinki Univ, Sch Pharmaceut Sci, Higashiosaka, Osaka 5778502, Japan

来源：

SYNLETT | 2011年 / 11期

基金：

日本学术振兴会;

关键词：

carboxylic acids; hypervalent iodine; halogenation; fluoroalchol; decarboxylation; CARBOXYLIC-ACIDS; DECARBOXYLATIVE PALLADATION; NUCLEOPHILIC-SUBSTITUTION; ORGANOHYPERVALENT IODINE; IODOSOBENZENE DIACETATE; FLUORINATED ALCOHOLS; HUNSDIECKER REACTION; ORGANIC-SYNTHESIS; BENZOIC-ACIDS; CHEMISTRY;

D O I：

10.1055/s-0030-1260791

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The novel reagent system, PhI(OAc)(2)-LiX combination in fluoroalcohol solvents, was found to be effective for halodecarboxylation of electron-rich arenecarboxylic acids. The method provided an efficient route to halogenated phenol ether derivatives.

引用

页码：1563 / 1566

页数：4

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