Studies on the reaction of 2,5-dichloro-3,6-dihydroxy1,4-benzoquinone with tribenzylamine and diazabicyclo[2.2.2]octane in acetonitrile solvent

被引：0

作者：

Dworniczak, M ^{[1
]}

机构：

[1] Adam Mickiewicz Univ Poznan, Fac Chem, PL-60780 Poznan, Poland

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2003年 / 79卷 / 02期

关键词：

chloranilic acid; anion radical; electron transfer reaction;

D O I：

10.1023/A:1024521815551

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of chloranilic acid with two nitrogen nucleophiles, tribenzylamine and diazabicyclo[2.2.2] octane has been studied. Careful spectroscopic analysis showed that the product in both cases is a radical ion pair of Q(.-), A(.+) type. Stoichiometry of the complex formed is of 1: 1 type. Mechanism of the reaction is proposed.

引用

页码：219 / 225

页数：7

共 23 条

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