3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one

被引:6
作者
Asad, Mohammad [2 ]
Oo, Chuan-Wei [2 ]
Osman, Hasnah [2 ]
Quah, Ching Kheng [1 ]
Fun, Hoong-Kun [1 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, Usm 11800, Penang, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
X-RAY; DIFFRACTION;
D O I
10.1107/S1600536810043837
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C18H10Cl2O4, the chromen-2-one ring system is almost planar [maximum deviation = 0.028 (1) angstrom] and is inclined at an angle of 16.35 (4)degrees with respect to the benzene ring. The C=C bond has an E configuration. The molecular conformation is stabilized by an almost symmetric intramolecular O center dot center dot center dot H center dot center dot center dot O hydrogen bond and a C-H center dot center dot center dot O interaction, both of which form S(6) ring motifs. In the crystal structure, molecules are linked into sheets lying parallel to (100) via intermolecular C-H center dot center dot center dot O hydrogen bonds. The crystal packing is further consolidated by pi-pi stacking interactions [centroid-to-centroid separation = 3.6615 (6) angstrom].
引用
收藏
页码:O3022 / U1954
页数:11
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