Ferrocenecarboxylic acid and microwave-assisted synthesis of ferrocenoyl hydrazones

被引：5
|
作者：
Kulikov, V. N. [1 ,2 ]
Nikulin, R. S. [1 ,2 ]
Arkhipov, D. E. [1 ]
Rodionov, A. N. [1 ]
Babusenko, E. S. [2 ]
Kovalenko, L. V. [2 ]
Belousov, Yu. A. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Ul Vavilova, Moscow 119991, Russia
[2] D Mendeleev Univ Chem Technol Russia, 9 Miusskaya Pl, Moscow 125047, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2017年 / 66卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
ferrocene; ferrocenecarboxylic acid; hydrazones; microwave-assisted synthesis; antimicrobial activity;
D O I：
10.1007/s11172-017-1768-x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A protocol to access ferrocenecarboxylic acid via carboxylation of ferrocene with carbon dioxide in the presence of aluminum chloride was elaborated. An efficient microwave-assisted synthesis of ferrocenoyl hydrazones by condensation of ferrocene carbohydrazide with carbonyl compounds was developed. Structures of the synthesized compounds were examined by NMR spectroscopy and mass spectrometry. Structures of N'-(4-chlorobenzylidene) ferrocene-carbohydrazide, N'-(4-methoxybenzylidene) ferrocenecarbohydrazide, and N'-(2-hydroxy-benzylidene) ferrocenecarbohydrazide were determined by X-ray diffraction analysis. Synthesized compounds were found to have no toxicity against P. aeruginosa, E. coli, S. aureus, B. subtilis, M. rubrum, and C. albicans.
引用
收藏
页码：537 / 544
页数：8
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