Anion Influence on the Solution-Solid Phase Equilibria in the MX2-NEt4X-H2O Systems (M = Cd, Cu, Co; X = Cl, Br) at 25°C

被引：0

作者：

Gusev, I. M. ^{[1
]}

Skripkin, M. Yu. ^{[1
]}

Burkov, K. A. ^{[1
]}

机构：

[1] St Petersburg State Univ, St Petersburg 198904, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

Complex Salt; Crystalline Hydrate; Solubility Isotherm; CdBr; Tetraethylammonium Chloride;

D O I：

10.1134/S107036321009001X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solubility of the ternary systems M-NEt4Cl-H2O (M = Cd, Cu, Co) at 25 degrees C was determined by the method of isothermal saturation. Compositions and fields of crystallization of solid compounds in equilibrium with a liquid phase were determined. Changes in the processes of hydration, association of tetraethyl ammonium salts, and acido-complex formation of d-element ions on the replacement of a halide anion affect the solution-solid phase equilibria in the studied systems.

引用

页码：1729 / 1732

页数：4

共 12 条

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