Asymmetric Bronsted acid catalysis in aqueous solution

被引：144
作者：
Rueping, Magnus [1 ]
Theissmann, Thomas [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源：
CHEMICAL SCIENCE | 2010年 / 1卷 / 04期
关键词：
DIELS-ALDER REACTIONS; VINYLOGOUS MANNICH REACTION; CARBON-CARBON BOND; ORGANOCATALYTIC TRANSFER HYDROGENATION; BAEYER-VILLIGER REACTION; DIRECT ALDOL REACTION; ORGANIC-REACTIONS; ENANTIOSELECTIVE REDUCTION; 3-SUBSTITUTED CYCLOBUTANONES; HYDROPHOBIC INTERACTIONS;
D O I：
10.1039/c0sc00206b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A biologically inspired reaction design leads to the development of the first highly enantioselective Bronsted acid catalysed reaction in aqueous solution.
引用
收藏
页码：473 / 476
页数：4
相关论文
共 66 条
[21]   Water in Stereoselective Organocatalytic Reactions [J].
Gruttadauria, Michelangelo ;
Giacalone, Francesco ;
Noto, Renato .
ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (1-2) :33-57
[22]   Enantioselective direct aldol reaction "on water" promoted by chiral organic catalysts [J].
Guizzetti, Stefania ;
Benaglia, Maurizio ;
Raimondi, Laura ;
Celentano, Giuseppe .
ORGANIC LETTERS, 2007, 9 (07) :1247-1250
[23]  
Hayashi, 2006, ANGEW CHEM, V118, P972
[24]   Highly diastereo- and enantioselective direct aldol reactions in water [J].
Hayashi, Y ;
Sumiya, T ;
Takahashi, J ;
Gotoh, H ;
Urushima, T ;
Shoji, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :958-961
[25]   In water or in the presence of water? [J].
Hayashi, Yujiro .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (48) :8103-8104
[26]   Highly efficient asymmetric direct stoichiometric aldol reactions on/in water [J].
Huang, Junmin ;
Zhang, Xiaotong ;
Armstrong, Daniel W. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (47) :9073-9077
[27]   L-GLUTAMATE DEHYDROGENASES - DISTRIBUTION, PROPERTIES AND MECHANISM [J].
HUDSON, RC ;
DANIEL, RM .
COMPARATIVE BIOCHEMISTRY AND PHYSIOLOGY B-BIOCHEMISTRY & MOLECULAR BIOLOGY, 1993, 106 (04) :767-792
[28]   Chiral Bronsted Acids for Asymmetric Organocatalysis [J].
Kampen, Daniela ;
Reisinger, Corinna M. ;
List, Benjamin .
ASYMMETRIC ORGANOCATALYSIS, 2009, 291 :395-456
[29]   Hydrophobic amplification of noncovalent organocatalysis [J].
Kleiner, Christian M. ;
Schreiner, Peter R. .
CHEMICAL COMMUNICATIONS, 2006, (41) :4315-4317
[30]   Development of novel Lewis acid catalysts for selective organic reactions in aqueous media [J].
Kobayashi, S ;
Manabe, K .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (04) :209-217
1234567