Synthesis of NiMoO4 nanorods on graphene and superior electrochemical performance of the resulting ternary based composites

被引:52
作者
Ezeigwe, Ejikeme Raphael [1 ,2 ]
Khiew, Poi Sim [2 ]
Siong, Chiu Wee [3 ]
Kong, Ing [2 ,4 ]
Tan, Michelle T. T. [1 ,2 ]
机构
[1] Univ Nottingham, Fac Engn, Dept Elect & Elect Engn, Malaysia Campus,Jalan Broga, Semenyih 43500, Selangor, Malaysia
[2] Univ Nottingham, Fac Engn, Ctr Nanotechnol & Adv Mat, Malaysia Campus,Jalan Broga, Semenyih 43500, Selangor, Malaysia
[3] Univ Malaya, Fac Sci, Low Dimens Mat Res Ctr, Dept Phys, Kuala Lumpur 50603, Malaysia
[4] Univ Nottingham, Dept Mech Mat & Mfg Engn, Malaysia Campus,Jalan Broga, Semenyih 43500, Selangor, Malaysia
关键词
NiMoO4; nanorods; Electrochemical capacitors; Liquid phase; Exfoliation of graphene; Ternary composites; SUPERCAPACITOR ELECTRODE MATERIALS; ENERGY-STORAGE; HYDROTHERMAL SYNTHESIS; NANOSHEETS; CARBON; NANOCOMPOSITE; ALPHA-NIMOO4; EXFOLIATION; CONVERSION; GROWTH;
D O I
10.1016/j.ceramint.2017.07.092
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
NiMoO4 nanorods have been directly synthesised on graphene sheet using a facile solvothermal method with subsequent calcination treatment. As an electrode for electrochemical capacitors, the graphene-NiMoO4 composite electrode prepared at a mass ratio of 1:8 exhibited a specific capacitance of 670 F/g at 0.3 A/g and good rate capability. When cycled at 0.5 A/g for 3000 cycles, it retained 88% of its initial capacitance with a Coulombic efficiency of similar to 80%. This study presents a pungent and environmental benign research strategy for the development of graphene-NiMoO4 ternary based electrochemical capacitors.
引用
收藏
页码:13772 / 13780
页数:9
相关论文
共 58 条
  • [1] Dynamic phenomena during reduction of α-NiMoO4 in different atmospheres:: In-situ thermo-Raman spectroscopy study
    Abdel-Dayem, Hany M.
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (08) : 2466 - 2472
  • [2] Aiping Yu J.Z., 2013, ELECTROCHEMICAL SUPE
  • [3] 2 D amorphous frameworks of NiMoO4 for supercapacitors: defining the role of surface and bulk controlled diffusion processes
    Ajay, Amrutha
    Paravannoor, Anjali
    Joseph, Jickson
    Amruthalakshmi, V
    Anoop, S. S.
    Nair, Shantikumar V.
    Balakrishnan, Avinash
    [J]. APPLIED SURFACE SCIENCE, 2015, 326 : 39 - 47
  • [4] [Anonymous], 1999, ELECTROCHEMICAL SUPE
  • [5] [Anonymous], MAT CHEM PHYS
  • [6] [Anonymous], 2015, GRAPHENE OXIDE REDUC, DOI DOI 10.1007/978-3-319-15500-5_3
  • [7] High-performance symmetric electrochemical capacitor based on graphene foam and nanostructured manganese oxide
    Bello, Abdulhakeem
    Fashedemi, Omobosede O.
    Lekitima, Joel N.
    Fabiane, Mopeli
    Dodoo-Arhin, David
    Ozoemena, Kenneth I.
    Gogotsi, Yury
    Johnson, Alan T. Charlie
    Manyala, Ncholu
    [J]. AIP ADVANCES, 2013, 3 (08):
  • [8] Carbon-based nanostructured materials and their composites as supercapacitor electrodes
    Bose, Saswata
    Kuila, Tapas
    Mishra, Ananta Kumar
    Rajasekar, R.
    Kim, Nam Hoon
    Lee, Joong Hee
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (03) : 767 - 784
  • [9] Facile hydrothermal synthesis of hierarchical ultrathin mesoporous NiMoO4 nanosheets for high performance supercapacitors
    Cai, Daoping
    Liu, Bin
    Wang, Dandan
    Liu, Yuan
    Wang, Lingling
    Li, Han
    Wang, Yanrong
    Wang, Chenxia
    Li, Qiuhong
    Wang, Taihong
    [J]. ELECTROCHIMICA ACTA, 2014, 115 : 358 - 363
  • [10] Comparison of the Electrochemical Performance of NiMoO4 Nanorods and Hierarchical Nanospheres for Supercapacitor Applications
    Cai, Daoping
    Wang, Dandan
    Liu, Bin
    Wang, Yanrong
    Liu, Yuan
    Wang, Lingling
    Li, Han
    Huang, Hui
    Li, Qiuhong
    Wang, Taihong
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (24) : 12905 - 12910