Genesis of new HDS catalysts through a careful control of the sulfidation of both Co and Mo atoms: Study of their activation under gas phase

被引：47

作者：

Frizi, Nayma ^{[1
]}

Blanchard, Pascal ^{[1
]}

Payen, Edmond ^{[1
]}

Baranek, Pascale ^{[1
]}

Rebeilleau, Michael ^{[2
]}

Dupuy, Carole ^{[2
]}

Dath, Jean Pierre ^{[2
]}

机构：

[1] Univ Sci & Technol, CNRS, UMR 8181, Unite Catalyse & Chim Solide, F-59655 Villeneuve Dascq, France

[2] Zone Ind, Total Petrochem Res, B-7181 Feluy, Belgium

来源：

CATALYSIS TODAY | 2008年 / 130卷 / 2-4期

关键词：

hydrotreatment; MoS2; thiophene; sulfidation; CoMo; catalysts; HDS; complexing agent; morphology;

D O I：

10.1016/j.cattod.2007.10.109

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Impregnation of oxidic precursor with thioglycolic acid aqueous solution was successfully used to improve the performances of thiophene hydrodesulfurization catalysts. Raman, EXAFS and XPS studies indicate that addition of this chelating agent affects the sulfidation of the supported metals. The higher catalytic performances were attributed to an optimization of the nature and morphology of the active phase obtained by the use of this chelating agent which permits a simultaneous sulfidation of both Co and Mo atoms. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：272 / 282

页数：11

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