Poly[[[ bis[(2,2′-bipyridine-κ2N,N′)cadmium(II)]-bis[μ3-3-(4-carboxylatophenoxy)propionato-κ5O,O′:O′:O",O"′]] 4-hydroxybenzoic acid monohydrate]

被引:1
作者
Kong, Li-Li
Gao, Shan
Huo, Li-Hua
Ng, Seik Weng [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词
D O I
10.1107/S1600536807054669
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The 3-(4-carboxylatophenoxy) propionate dianion in the title compound, [Cd-2(C10H8O5)(2)(C10H8N2)(2)]center dot C7H6O3 center dot H2O, linksadjacent metal atoms into a chain, the dianion chelating through both O atoms of its two -CO2- end groups. One of the carboxylate O atoms (that belonging to the aliphatic carboxylate end) engages in interchain coordination, linking two chains into a ribbon. The ribbons are linked to the disordered water molecule and 4-hydroxybenzoic acid by O-H center dot center dot center dot O hydrogen bonds, further consolidating the ribbon motif. The Cd-II atom exists in a seven-coordinate CdN2O5 enviroment that approximates to a monocapped octahedron. The dinuclear repeat unit is centrosymmetric.
引用
收藏
页码:M2938 / U748
页数:15
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