Mild oxidation of hydrocarbons by tert-butyl hydroperoxide catalyzed by electron deficient manganese(III) corroles

被引：26

作者：

Bose, Suranjana ^{[1
]}

Pariyar, Anand ^{[1
]}

Biswas, Achintesh Narayan ^{[1
]}

Das, Purak ^{[1
]}

Bandyopadhyay, Pinaki ^{[1
]}

机构：

[1] Univ N Bengal, Dept Chem, Siliguri 734013, W Bengal, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2010年 / 332卷 / 1-2期

关键词：

Manganese corrole; Catalysis; Oxygenation; tert-Butyl hydroperoxide; SCHIFF-BASE COMPLEXES; SATURATED-HYDROCARBONS; ALKANE OXIDATION; METAL; FUNCTIONALIZATION; MECHANISM; OXYGENATIONS; ACTIVATION; METALLOCORROLES; ATHEROSCLEROSIS;

D O I：

10.1016/j.molcata.2010.09.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mild oxidations of alkenes with tert-butylhydroperoxide catalyzed by electron deficient manganese(III) corroles have been achieved at room temperature. The oxygenation of cyclohexane, adamantane and toluene has also been studied under similar reaction conditions. The oxidation has been shown to proceed with participation of alkylperoxy (ROO center dot) radicals and organo-hydroperoxide (ROOH). A reaction mechanism is proposed based on the experimental results. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1 / 6

页数：6

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