Synthesis of nano-RuAl by mechanical alloying

被引:22
作者
Liu, KW [1 ]
Mücklich, F [1 ]
Birringer, R [1 ]
机构
[1] Univ Saarlandes, Lehrstuhl Funktionswerkstoffe, D-66123 Saarbrucken, Germany
关键词
nanostructured intermetallics (including preparation methods); thermal stability; mechanical alloying and milling;
D O I
10.1016/S0966-9795(00)00100-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Single phase RuAl has been synthesised directly by an abrupt reaction during mechanical alloying (MA). The structural evolution during MA and subsequent thermal stability of as- milled powders have been analysed by thermal analysis (DSC) and isothermal annealing. The results indicate that there are two stages of alloying and reaction between Ru and Al in MA before single phase RuAl is obtained under the present milling conditions, and that the as-milled single phase RuAl undergoes reordering, strain relaxation and grain growth at high temperatures. The grain size of 20-40 nm after annealing at 1073 K for 0.5 h shows a strong stability of the nano-grained RuAl. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:81 / 88
页数:8
相关论文
共 19 条
[1]   MECHANICAL ALLOYING [J].
BENJAMIN, JS .
SCIENTIFIC AMERICAN, 1976, 234 (05) :40-49
[2]   NANOCRYSTALLINE INTERMETALLIC COMPOUNDS - AN APPROACH TO DUCTILITY [J].
BOHN, R ;
HAUBOLD, T ;
BIRRINGER, R ;
GLEITER, H .
SCRIPTA METALLURGICA ET MATERIALIA, 1991, 25 (04) :811-816
[3]  
Cullity BD, 1978, ELEMENTS XRAY DIFFRA
[4]   BORON AND OFF-STOICHIOMETRY EFFECTS ON THE STRENGTH AND DUCTILITY OF ALRU [J].
FLEISCHER, RL .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1993, 24 (01) :227-230
[5]   STABILITY OF CSCL-TYPE INTERMETALLIC COMPOUNDS UNDER BALL MILLING [J].
HELLSTERN, E ;
FECHT, HJ ;
FU, Z ;
JOHNSON, WL .
JOURNAL OF MATERIALS RESEARCH, 1989, 4 (06) :1292-1295
[6]   STRUCTURAL AND THERMODYNAMIC PROPERTIES OF HEAVILY MECHANICALLY DEFORMED RU AND AIRU [J].
HELLSTERN, E ;
FECHT, HJ ;
FU, Z ;
JOHNSON, WL .
JOURNAL OF APPLIED PHYSICS, 1989, 65 (01) :305-310
[7]   STANDARD MOLAR ENTHALPIES OF FORMATION OF MEAL (ME = RU, RH, OS, IR) [J].
JUNG, WG ;
KLEPPA, OJ .
METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY, 1992, 23 (01) :53-56
[8]  
KLUG HP, 1974, XRAY DIFFRACTION PRO, P661
[9]   Overview paper no. 2. The synthesis and structure of nanocrystalline materials produced by mechanical attrition. A review [J].
Koch, C.C. .
Nanostructured Materials, 1993, 2 (02)
[10]   Formation of intermetallic nanocomposites in the Ti-Al-Si system by mechanical alloying and subsequent heat treatment [J].
Liu, KW ;
Zhang, JS ;
Wang, JG ;
Chen, GL .
JOURNAL OF MATERIALS RESEARCH, 1998, 13 (05) :1198-1203