Ultrasensitive all-solid-state electrochemiluminescence platform for kanamycin detection based on the pore confinement effect of 0D g-C3N4 quantum dots/3D graphene hydrogel

被引:22
作者
Jiang, Ding [1 ,2 ]
Qin, Ming [1 ]
Zhang, Linhua [1 ]
Shan, Xueling [1 ,2 ]
Chen, Zhidong [1 ,2 ]
机构
[1] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Sch Petrochem Engn, Changzhou 213164, Peoples R China
[2] Changzhou Univ, Adv Catalysis & Green Mfg Collaborat Innovat Ctr, Changzhou 213164, Peoples R China
基金
中国国家自然科学基金;
关键词
Electrochemiluminescence; Graphene hydrogel; Kanamycin; g-C3N4; CARBON NITRIDE; GOLD NANOPARTICLES; PERFORMANCE; ELECTROCHEMISTRY; HETEROJUNCTION; TETRACYCLINE; SEPARATION; STRATEGY; FACILE;
D O I
10.1016/j.snb.2021.130343
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Quests for stable and highly efficient electrochemiluminescence (ECL) emitters and a full understanding of the relation between the ECL emitter structure and its properties are a continual and active theme in the fields of ECL. In this work, an intense and stable ECL platform was achieved by encapsulating 0D graphite carbon nitride quantum dots (g-C3N4 QDs) into 3D graphene hydrogel via a facile hydrothermal approach. The architectures of the as-fabricated 0D g-C3N4 QDs/3D graphene hydrogel nanocomposites showed 4.3-fold ECL intensity relative to that of pure g-C3N4. This phenomenon was caused by a pore confinement effect, which could increase the electrochemical reaction efficiency because the pore channels could promote electron transfer and mass transport. The confinement effect could also localise a very large luminophore near the electrode surface, resulting in enhanced ECL emission. Moreover, the as-fabricated architecture ensured the stability of the g-C3N4 QDs in the ECL field due to the increased dispersibility. On the basis of the excellent ECL performances, a novel ECL biosensor was fabricated for highly selective and sensitive detection of kanamycin (KAN) with the assistance of an aptamer. The proposed ECL sensor can quantify KAN from 1 pM to 50 nM with a limit of detection of 0.33 pM. Such work offers an efficient design idea for achieving a high-performance ECL platform and provides new insight into developing and applying a g-C3N4-based ECL system.
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页数:7
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