Chemical, Electrochemical and Quantum Chemical Studies for Famotidine Drug as a Safe Corrosion Inhibitor for α-Brass in HCl Solution

被引:41
|
作者
Fouda, A. S. [1 ]
Ahmed, R. E. [1 ]
El-Hossiany, A. [1 ,2 ]
机构
[1] Mansoura Univ, Fac Sci, Dept Chem, Mansoura 35516, Egypt
[2] Delta Fertilizers Co Talkha, Talkha, Egypt
关键词
alpha-brass; famotidine; EFM; EIS; AFM; FT; IR; SEM; EDX; HCl; MILD-STEEL; FREQUENCY-MODULATION; CARBON-STEEL; MONITORING CORROSION; COPPER CORROSION; ACID CORROSION; PURE IRON; ADSORPTION; SURFACTANT; ALUMINUM;
D O I
10.1134/S207020512101010X
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Expired Famotidine was tested as a corrosion protection for alpha-brass in 1 M HCl using modified methods: weight loss (WL), Tafel polarization (TP), AC impedance spectra (EIS) and electrochemical frequency modulation (EFM). The polarization resistance (R-p) data increased with increasing famotidine dose. The inhibition efficiency (IE) improved with raising famotidine concentration. The maximum IE of 90% has been achieved at 300 ppm. On the other hand, the efficiency lowered with temperature increased. The outcome data obtained revealed that famotidine performed excellently as a corrosion inhibitor for alpha-brass in this medium at dissimilar temperatures. The surface of alpha-brass was tested utilizing scanning electron microscope (SEM), energy dispersion spectroscopy X-ray spectra (EDX), Fourier transform infrared spectroscopy (FT-IR), and atomic force microscopy (AFM analysis).
引用
收藏
页码:398 / 411
页数:14
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