An improved protocol for the synthesis of antipodal β-tetrabromo-tetraphenylporphyrin and the crystal structure of its Zn(II) complex

被引:102
作者
Kumar, PK [1 ]
Bhyrappa, P [1 ]
Varghese, B [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
关键词
D O I
10.1016/S0040-4039(03)01143-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This work reports an improved protocol for the regioselective synthesis of 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin (H2TPPBr4) and the crystal structure of its Zn(II) complex which shows saddle shaped geometry. (C) 2003 Elsevier Science Ltd. All rights reserved.
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收藏
页码:4849 / 4851
页数:3
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