Supramolecular helix-to-helix induction: A 3D anionic framework containing double-helical strands templated by cationic triple-stranded cluster helicates

被引：99

作者：

Hou, Jin-Zhang ^{[1
]}

Li, Mian ^{[1
]}

Li, Zhen ^{[1
]}

Zhan, Shun-Ze ^{[1
]}

Huang, Xiao-Chun ^{[1
]}

Li, Dan ^{[1
]}

机构：

[1] Shantou Univ, Dept Chem, Guangdong 515063, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 09期

关键词：

chirality transfer; coordination polymers; copper; helical structures; template synthesis;

D O I：

10.1002/anie.200704874

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) All wrapped up: Supramolecular polymeric helices were fabricated by using cluster helicates as templates. The helicity of the template (see picture; gold spheres: Ni or Zn; blue spheres: O), upon hydrothermal treatment with CuSCN (gray spheres), is transferred to the strands of the resulting copper-based coordination polymer, which is wrapped around the helicate units in the final product. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1711 / 1714

页数：4

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