Palladium-Catalyzed Selective Acyloxylation Using Sodium Perborate as Oxidant

被引：42

作者：

Pilarski, Lukasz T. ^{[1
]}

Janson, Par G. ^{[1
]}

Szabo, Kalman J. ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 05期

基金：

瑞典研究理事会;

关键词：

M-CHLOROPERBENZOIC ACID; ALLYLIC ACETOXYLATION; ORGANIC-SYNTHESIS; TERMINAL OLEFINS; MOLECULAR-OXYGEN; OXIDATION; FUNCTIONALIZATION; ALKENES; PERCARBONATE; BENZOQUINONE;

D O I：

10.1021/jo1024199

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sodium perborate (SPB), a principal component of washing powders, was employed as an inexpensive and eco-friendly oxidant in the palladium-catalyzed C-H acyloxylation of alkenes in excellent regio- and stereochemistry. The reactions used anhydrides as acyloxy sources. The method applies to both terminal and internal alkenes, and even benzylic C-H oxidation.

引用

页码：1503 / 1506

页数：4

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