Organolanthanide-catalyzed cyclization/boration of 1,5-and 1,6-dienes

被引：46

作者：

Molander, GA ^{[1
]}

Pfeiffer, D ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 03期

关键词：

D O I：

10.1021/ol006841s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] 1,5- and 1,6-Dienes undergo a cyclization/boration reaction in the presence of a catalytic amount of Cp*Sm-2 . THF. The resulting organoboranes can be oxidized to the corresponding primary cyclic alcohols using standard conditions.

引用

页码：361 / 363

页数：3

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